Synthetic communications

Palladium-catalyzed preparation of dialkyl allylphosphonates. A new preparation of diethyl 2-oxoethylphosphonate

R Malet, M Moreno-Manas, R Pleixats

Index: Malet; Moreno-Manas; Pleixats Synthetic Communications, 1992 , vol. 22, # 15 p. 2219 - 2228

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Citation Number: 23

Abstract

... halides. This is the well known Michaelis-Arbuzov reacti0n.l Palladium-catalyzed attack of nucleophiles on allyl acetates and carbonates is a well established synthetic method of broad 2219 ... 11.0 Hz); MS(m/e): 220(M, 4), 163(14), 136(100), 96(23), 55(16), 43(31). Page 8. 2226