Triisopropyl phosphite

Modify Date: 2024-01-02 15:57:01

Triisopropyl phosphite Structure
Triisopropyl phosphite structure
Common Name Triisopropyl phosphite
CAS Number 116-17-6 Molecular Weight 208.235
Density 0.914 Boiling Point 181.4±0.0 °C at 760 mmHg
Molecular Formula C9H21O3P Melting Point N/A
MSDS Chinese USA Flash Point 67.8±0.0 °C
Symbol GHS06
GHS06
Signal Word Danger

 Names

Name Triisopropyl phosphite
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.914
Boiling Point 181.4±0.0 °C at 760 mmHg
Molecular Formula C9H21O3P
Molecular Weight 208.235
Flash Point 67.8±0.0 °C
Exact Mass 208.122833
PSA 41.28000
LogP 1.71
Vapour Pressure 1.2±0.3 mmHg at 25°C
Index of Refraction n20/D 1.411(lit.)
Water Solubility Insoluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH2800000
CHEMICAL NAME :
Phosphorous acid, tris(1-methylethyl) ester
CAS REGISTRY NUMBER :
116-17-6
BEILSTEIN REFERENCE NO. :
1701528
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C9-H21-O3-P
MOLECULAR WEIGHT :
208.27
WISWESSER LINE NOTATION :
1Y1&OPOY1&1&OY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
167 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TEST SYSTEM :
Insect - Drosophila melanogaster
DOSE/DURATION :
50 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 28,405,1975

 Safety Information

Symbol GHS06
GHS06
Signal Word Danger
Hazard Statements H301-H315
Precautionary Statements Missing Phrase - N15.00950417
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T:Toxic;
Risk Phrases R25;R38;R68
Safety Phrases S37-S46-S45-S36/37
RIDADR UN 3278 6.1/PG 3
WGK Germany 3
RTECS TH2800000
Packaging Group III
Hazard Class 3

 Synthetic Route

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Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , p. 237,241 Chem. Zentralbl., , vol. 121, p. 8713 Annali di Chimica (Rome, Italy), , vol. 43, p. 568,571,572 Industrial and Engineering Chemistry, , vol. 43, p. 876,878

~0%

Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: Collins, David J.; Drygala, Peter F.; Swan, John M. Australian Journal of Chemistry, 1983 , vol. 36, # 12 p. 2517 - 2536

~65%

Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: Al'fonsov, V. A.; Pudovik, D. A.; Musin, R. Z.; Nazmutdinova, V. N.; Efremov, Yu. Ya.; et al. J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 8 p. 1734 - 1740,1548 - 1553

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Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: Journal of the Chemical Society, Perkin Transactions 2, , # 11 p. 2159 - 2165

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Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 58, # 8 p. 1734 - 1740,1548 - 1553

~%

Detail
Literature: Journal of the Chemical Society, , p. 422,424

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Triisopropyl phosphite Structure

Triisopropyl ph...

CAS#:116-17-6

Literature: Journal of the Chemical Society, , p. 1466

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Detail
Literature: Zhurnal Obshchei Khimii, , vol. 17, p. 2129,2132 Chem.Abstr., , p. 4546

 Articles2

More Articles
Surface characterization and platelet adhesion studies of plasma polymerized phosphite and its copolymers with dimethylsulfate.

Biomaterials 20(16) , 1439-47, (1999)

Due to its capability for using a wide variety of organic and inorganic compounds as the monomer source, including those which are not polymerizable by conventional methods, plasma polymerization has ...

Environmental change in Jiaozhou Bay recorded by nutrient components in sediments.

Mar. Pollut. Bull. 60(9) , 1591-9, (2010)

Inorganic or bulk organic chemical indicators, including organic carbon (OC), total nitrogen, organic nitrogen (ON), fixed ammonium (N(fix)), exchangeable ammonium, exchangeable nitrate, organic phosp...

 Synonyms

EINECS 204-130-0
tripropan-2-yl phosphite
Medronic acid impurity A
Triisopropyl phosphite
Phosphorous acid, triisopropyl ester (8CI)
Phosphorous acid, tris(1-methylethyl) ester
MFCD00008874
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