Tetrahedron letters

Novel oxidative cleavage of carbon—carbon bond in hydrazones by oxygenation with cobalt Schiff base complex

A Nishinaga, S Yamazaki, T Matsuura

Index: Nishinaga, Akira; Yamazaki, Shigekazu; Matsuura, Teruo Tetrahedron Letters, 1986 , vol. 27, # 23 p. 2649 - 2652

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Citation Number: 18

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Oxygenation of aromatic ketone hydrazones with Co(salen) in methanol resulted unexpectedly in oxidative degradation to give methyl benzoate derivatives. A mechanism involving nucleophilic attack by methanol on a diazo intermediate is discussed. ... Co(salen) promoted ...