Palladium??Catalyzed Carbonylative Synthesis of Phthalimides from 1, 2??Dibromoarenes with Molybdenum Hexacarbonyl as Carbon Monoxide Source

…, A Flader, L Krey, M Beller, P Langer

Index: Wu, Xiao-Feng; Oschatz, Stefan; Sharif, Muhammad; Flader, Anika; Krey, Lisa; Beller, Matthias; Langer, Peter Advanced Synthesis and Catalysis, 2013 , vol. 355, # 18 p. 3581 - 3585

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Citation Number: 14

Abstract

Abstract: We describe here a convenient and mild, carbon monoxide gas-free palladium- catalyzed procedure to obtain N-substituted phthalimides with molybdenum hexacarbonyl as carbon monoxide precursor. These conditions tolerate a number of functional groups on the benzene ring as well as a number of amines and give the corresponding phthalimides in good to excellent yields. Keywords: aminocarbonylation; 1, 2-dibromoarenes; ...