Chemical communications

Nickel-catalyzed coupling of isocyanates with 1, 3-iodoesters and halobenzenes: a novel method for the synthesis of imide and amide derivatives

JC Hsieh, CH Cheng

Index: Hsieh, Jen-Chieh; Cheng, Chien-Hong Chemical Communications, 2005 , # 36 p. 4554 - 4556

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Citation Number: 16

Abstract

Isocyanate derivatives are very reactive species, but the application of isocyanates is mostly limited to the synthesis of urethane or urea derivatives. 1 Only recently, transition metal-mediated cycloaddition of isocyanates with alkynes to form pyridones has attracted considerable attention. 2 On the other hand, imides are important industrial, biological and medicinal chemicals. 3,4 A common method for the preparation of imides is via condensation of ...

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