Journal of organometallic chemistry

Novel method for preparing bis (trimethylsilyl) amines via treatment with trimethylsilylamines and methyl iodide

Y Hamada, Y Yamamoto, H Shimizu

Index: Hamada, Yoshitaka; Yamamoto, Yasushi; Shimizu, Hideaki Journal of Organometallic Chemistry, 1996 , vol. 510, # 1-2 p. 1 - 6

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Citation Number: 9

Abstract

A convenient method for the synthesis of N, N-bis (trimethylsilyl) alkylamines has been reported. N-(Trimethylsilyl) diethylamine incorporated with a stoichiometric amount of methyl iodide was effective to convert primary amines, especially aromatic amines, and their monotrimethylsilyl derivatives into the corresponding N, N-bis (trimethylsilyl) amine derivatives in high yields. In the case of N-trimethylsilyl derivatives of aliphatic primary ...