CONTRIBUTIONS TO THE CHEMISTRY OF ORGANIC SILICON-NITROGEN-COMPOUNDS, I

M Schorr, W Schmitt

Index: Schorr, Manfred; Schmitt, Wilfried Phosphorus, Sulfur and Silicon and the Related Elements, 1992 , vol. 68, # 1-4 p. 25 - 36

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Citation Number: 4

Abstract

Abstract The preparation of N, N-bis-(trimethylsilyl) amines has been investigated. Three convenient methods are reported: A, Transfer of (catalytically) activated Tms-groups to amines starting from N-silylated carbonamides, B, silylation of amines with trimethylsilylchloride/NEt3, in the presence of TiCl4, C, silylation of primary amines or mono- (trimethylsi! yl) amines wi [h CF3SO3 Tms/NEt3 or Tms/NEt3. Methods A and B are limited ...