… (2+)-mediated photoreduction of olefins with 1-benzyl-1, 4-dihydronicotinamide: a mechanistic probe for electron-transfer reactions of NAD (P) H-model compounds

C Pac, M Ihama, M Yasuda, Y Miyauchi…

Index: Pac,C.; Ihama,M.; Yasuda,M. Journal of the American Chemical Society, 1981 , vol. 103, p. 6495

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Citation Number: 80

Abstract

4a (4b) 4 9 several olefins which are unreactive with 1,+ dihydropyridines in the dark at room temperat~ re~-~ can be reduced by l-benzyl-1, 4-dihydronicotinamide (BNAH) upon selective photoexcitation of Ru (bpy):+(bpy= 2, 2'-bipyridine) and that the photomediated two- electron reduction proceeds by way of sequential electron transfer.