Chemistry–A European Journal

Copper??Catalyzed Oxidative Amination and Allylic Amination of Alkenes

TW Liwosz, SR Chemler

Index: Liwosz, Timothy W.; Chemler, Sherry R. Chemistry - A European Journal, 2013 , vol. 19, # 38 p. 12771 - 12777

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Citation Number: 57

Abstract

Abstract Enamines and enamides are useful synthetic intermediates and common components of bioactive compounds. A new protocol for their direct synthesis by a net alkene C [BOND] H amination and allylic amination by using catalytic Cu II in the presence of MnO 2 is reported. Reactions between N-aryl sulfonamides and vinyl arenes furnish enamides, allylic amines, indoles, benzothiazine dioxides, and dibenzazepines directly ...

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