Journal of Fluorine Chemistry

A simple convenient method for preparation of difluoromethyl ethers using fluorosulfonyldifluoroacetic acid as a difluorocarbene precursor

QY Chen, SW Wu

Index: Chen, Qing-Yun; Wu, Sheng-Wen Journal of Fluorine Chemistry, 1989 , vol. 44, p. 433 - 440

Full Text: HTML

Citation Number: 42

Abstract

Abstract In the presence of catalytic amounts of sodium sulfate or cuprous iodide, a variety of alkyl and aryl difluoromethyl ethers were synthesized in moderate yields by the reaction of the corresponding alcohols and phenols with fluorosulfonyldifluoroacetic acid (1) in

~43%

~54%

~58%

~31%

~42%

~48%

Three step procedure for the preparation of aromatic and ali...

[Dolbier Jr., William R.; Wang, Fei; Tang, Xiaojun; Thomoson, Charles S.; Wang, Linhua Journal of Fluorine Chemistry, 2014 , vol. 160, p. 72 - 76]

Chlorodifluoromethyl aryl ketones and sulfones as difluoroca...

[Wang, Fei; Zhang, Laijun; Zheng, Ji; Hu, Jinbo Journal of Fluorine Chemistry, 2011 , vol. 132, # 8 p. 521 - 528]

Preparation of (phenyldifluoromethyl)-and (phenoxydifluorome...

[Guidotti, Jerome; Metz, Francois; Tordeux, Marc; Wakselman, Claude Synlett, 2004 , # 10 p. 1759 - 1762]

Synthetic and mechanistic aspects of halo-F-methylphosphonat...

[Flynn, Richard M.; Burton, Donald J. Journal of Fluorine Chemistry, 2011 , vol. 132, # 10 p. 815 - 828]

Oxidation of Primary Aliphatic and Aromatic Aldehydes with D...

[Ochiai, Masahito; Yoshimura, Akira; Hoque, Md. Mahbubul; Okubo, Takuji; Saito, Motomichi; Miyamoto, Kazunori Organic Letters, 2011 , vol. 13, # 20 p. 5568 - 5571]