Journal of organometallic chemistry

New synthetic route to N-acyl-α-amino acids via amidocarbonylation by means of homogeneous binary catalyst systems

I Ojima, K Hirai, M Fujita, T Fuchikami

Index: Hirai, Kenji; Fujita, Makoto; Fuchikami, Takamasa Journal of Organometallic Chemistry, 1985 , vol. 279, p. 203 - 214

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Citation Number: 51

Abstract

Abstract New catalytic processes which lead to the formation of N-acyl-α-amino acids promoted by homogeneous binary systems are described:(a) the isomerization- amidocarbonylation of allyllic alcohols catalyzed by transition metal binary systems, eg, Co- Rh, Co-Pd, Co-Fe, giving various aliphatic N-acyl-α-amino acids;(b) the isomerization- amidocarbonylation of oxiranes catalyzed by cobalt-Lewis acid systems giving N-acyl-α- ...