The Divergent Transformations of Aromatic o??Aminonitrile with Carbonyl Compound

…, L Zhang, S Ma, D Shi, Q Zhang, L Yang…

Index: Tang, Jianhong; Li, Jiarong; Zhang, Lijun; Ma, Shuling; Shi, Daxin; Zhang, Qi; Yang, Liupan; Wang, Xiuzhen; Liu, Xuan; Liu, Change Journal of Heterocyclic Chemistry, 2012 , vol. 49, # 3 p. 533 - 542

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Citation Number: 14

Abstract

Abstract A modified Friedländer conversion of the cyclocondensation of aromatic o- aminonitriles with carbonyl compounds was discovered. Systematic studies reveal that both the new transformation and the classic Friedländer annulation in the presence of ZnCl 2 constitute a pair of divergent reaction, and thecontrolled PDF transformation of this divergent reaction was achieved in the present of bases.