Chemistry–An Asian Journal

Triazole??Functionalized N??Heterocyclic Carbene Complexes of Palladium and Platinum and Efficient Aqueous Suzuki–Miyaura Coupling Reaction

S Gu, H Xu, N Zhang, W Chen

Index: Gu, Shaojin; Xu, Hui; Zhang, Na; Chen, Wanzhi Chemistry - An Asian Journal, 2010 , vol. 5, # 7 p. 1677 - 1686

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Citation Number: 89

Abstract

Abstract Imidazolium salts bearing triazole groups are synthesized via a copper catalyzed click reaction, and the silver, palladium, and platinum complexes of their N-heterocyclic carbenes are studied.[Ag 4 (L1) 4](PF 6) 4,[Pd (L1) Cl](PF 6),[Pt (L1) Cl](PF 6)(L1= 3-((1- benzyl-1H-1, 2, 3-triazol-4-yl) methyl)-1-(pyrimidin-2-yl)-1H-imidazolylidene),[Pd 2 (L2) 2 Cl 2](PF 6) 2, and [Pd (L2) 2](PF 6) 2 (L2= 1-butyl-3-((1-(pyridin-2-yl)-1H-1, 2, 3-triazol-4-yl) ...