Tetrahedron

The functionalization of saturated hydrocarbons. Part 26. Ionic substitution reactions in GoAgg IV chemistry: The construction of C N, C S and C C bonds

DHR Barton, W Chavasiri

Index: Barton, Derek H. R.; Warinthorn, Chavasiri Tetrahedron, 1994 , vol. 50, # 1 p. 47 - 60

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Citation Number: 17

Abstract

Utilization of the GoAggIV system in the presence of sodium azide, sodium nitrite, sodium thiocyanate, sodium disulfide and tetraethylamonium cyanide converts saturated hydrocarbons into the corresponding alkyl azides, nitroalkanes, alkyl thiocyanates, dialkyl disulfides and alkyl cyanides, respectively. Mechanistic studies suggest an Fe-centered ligand coupling reaction pathway.

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Detail

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