Autoxidation and Condensation Reactions of Carbanions in Dimethyl Sulfoxide Solution

GA Russell, EG Janzen, HD Becker…

Index: Russell,G.A. et al. Journal of the American Chemical Society, 1962 , vol. 84, p. 2652 - 2653

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Citation Number: 68

Abstract

(1) Reactions ol Resonance Stabilized Anion-. 11.(2) EJ Carey and XI Chaykuvsky, J. A m C. hc, m Sic. 84, Xtili (1962), methyl sulfoxide solution---a study which has led to an investigation of condensation and addition reactions involving dimethyl sulfoxide. Although solutions of alkoxides in dimethyl sulfoxide react with oxygen yielding dimethyl sulfone and methanesulfonic acid, mixtures of dimethyl sulfoxide and t-butyl alcohol are stable to ...