3-ETHOXYMETHACROLEIN

Modify Date: 2024-01-04 19:46:04

3-ETHOXYMETHACROLEIN Structure
3-ETHOXYMETHACROLEIN structure
Common Name 3-ETHOXYMETHACROLEIN
CAS Number 42588-57-8 Molecular Weight 114.14200
Density 0.915 g/cm3 Boiling Point 191ºC at 760 mmHg ,78-81ºC14 mm Hg(lit.)
Molecular Formula C6H10O2 Melting Point N/A
MSDS Chinese USA Flash Point 57.5ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name 3-Ethoxymethacrolein
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.915 g/cm3
Boiling Point 191ºC at 760 mmHg ,78-81ºC14 mm Hg(lit.)
Molecular Formula C6H10O2
Molecular Weight 114.14200
Flash Point 57.5ºC
Exact Mass 114.06800
PSA 26.30000
LogP 1.12560
Index of Refraction n20/D 1.4792(lit.)
Storage condition 0-6°C

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H302 + H312 + H332
Precautionary Statements P280
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases 36
RIDADR UN 1993
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2912499000

 Synthetic Route

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3-ETHOXYMETHACROLEIN Structure

3-ETHOXYMETHACROLEIN

CAS#:42588-57-8

Literature: Klimko,V.T. et al. J. Gen. Chem. USSR (Engl. Transl.), 1962 , vol. 32, p. 2961 - 2966,2913 - 2918

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3-ETHOXYMETHACROLEIN Structure

3-ETHOXYMETHACROLEIN

CAS#:42588-57-8

Literature: Nair,V.; Vietti,D.E.; Cooper,C.S. Journal of the American Chemical Society, 1981 , vol. 103, p. 3030

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Detail
Literature: Sydnes, Leiv K.; Bakstad, Einar Acta Chemica Scandinavica, 1996 , vol. 50, # 5 p. 446 - 453

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Detail
Literature: Sydnes, Leiv K.; Bakstad, Einar Acta Chemica Scandinavica, 1996 , vol. 50, # 5 p. 446 - 453

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3-ETHOXYMETHACROLEIN Structure

3-ETHOXYMETHACROLEIN

CAS#:42588-57-8

Literature: Stavrovskaya,A.V. et al. Zhurnal Organicheskoi Khimii, 1968 , vol. 4, p. 1194 - 1198,1148 - 1151

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3-ETHOXYMETHACROLEIN Structure

3-ETHOXYMETHACROLEIN

CAS#:42588-57-8

Literature: Ullrich, Friedrich-Wilhelm; Rotscheidt, Klaus; Breitmaier, Eberhard Chemische Berichte, 1986 , vol. 119, # 5 p. 1737 - 1744

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3-ETHOXYMETHACROLEIN Structure

3-ETHOXYMETHACROLEIN

CAS#:42588-57-8

Literature: Babler, James H.; Liptak, Vincent P.; Trautmann, Jeffrey A.; Zayia, Gregory H. Synthetic Communications, 1996 , vol. 26, # 10 p. 1943 - 1951

 Customs

HS Code 2912499000
Summary 2912499000. other aldehyde-ethers, aldehyde-phenols and aldehydes with other oxygen function. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%

 Articles3

More Articles
Synthesis of quinolines via ortho-lithiated N-acylanilines. A modified Friedlaender synthesis. Cho IS, et al.

J. Org. Chem. 56(26) , 7288-7291, (1991)

Photooxygenation of chiral dienol ethers: asymmetric synthesis of alkoxydioxines. Dussault PH, et al.

Tetrahedron 55(38) , 11437-54, (1999)

A simplified and efficient synthesis of 5,10-dideaza-5,6,7,8-tetrahydrofolic acid (DDATHF).

Invest. New Drugs 14(3) , 281-5, (1996)

A new and extremely efficient synthesis of DDATHF from 4-vinylbenzoic acid and bromomalondialdehyde as precursors has been developed which proceeds in 48% overall yield.

 Synonyms

3-ETHOXYMETHACROLEIN
EINECS 255-899-4
MFCD00006975
3-Ethoxy-2-methylpropenal