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5373-87-5

5373-87-5 structure
5373-87-5 structure
  • Name: N-HYDROXY-4-METHOXY-BENZAMIDINE
  • Chemical Name: N'-Hydroxy-4-methoxybenzenecarboximidamide,
  • CAS Number: 5373-87-5
  • Molecular Formula: C8H10N2O2
  • Molecular Weight: 166.17700
  • Create Date: 2018-09-22 22:33:20
  • Modify Date: 2024-01-08 22:49:32

Name N'-Hydroxy-4-methoxybenzenecarboximidamide,
Synonyms 4-Methoxybenzamide oxime
N-HYDROXY-4-METHOXY-BENZAMIDINE
N'-HYDROXY-4-METHOXYBENZENECARBOXIMIDAMIDE
p-anisamidoxime
anisamidoxime
4-Methoxybenzamidoxime
4-methoxyphenylcarboxamidoxime
N'-Hydroxy-4-methoxybenzenecarboximideamide
p-methoxybenzamide oxime
4-Methoxybenzenecarboxamide oxime
n-hydroxy-4-methoxy-benzenecarboximidamid
N-hydroxy-4-methoxybenzimidamide
4-methoxybenzamidoxime
Density 1.21g/cm3
Boiling Point 344.8 °C at 760 mmHg
Melting Point 122-128℃
Molecular Formula C8H10N2O2
Molecular Weight 166.17700
Exact Mass 166.07400
PSA 67.84000
LogP 1.49000
Storage condition 2-8°C
Name: N -Hydroxy-4-methoxybenzenecarboximidamide Material Safety Data Sheet
Synonym:
CAS: 5373-87-5
Section 1 - Chemical Product MSDS Name:N -Hydroxy-4-methoxybenzenecarboximidamide Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
5373-87-5 Vinyl Sulfone polystyrene resin 95+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38 44

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin. Risk of explosion if heated under confinement.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Violently decomposes when heated under confinement.
Risk of explosion if heated under confinement.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 5373-87-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: Off white
Odor: Without to slight
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 122 - 128 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H10N2O2
Molecular Weight: 166.18

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases, peroxides.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 5373-87-5: BZ3425000 LD50/LC50:
Not available.
Carcinogenicity:
Vinyl Sulfone polystyrene resin - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 44 Risk of explosion if heated under confinement.
Safety Phrases:
S 22 Do not breathe dust.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 5373-87-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 5373-87-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 5373-87-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BZ3425000
CHEMICAL NAME :
p-Anisamidoxime
CAS REGISTRY NUMBER :
5373-87-5
LAST UPDATED :
199206
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C8-H10-N2-O2
MOLECULAR WEIGHT :
166.20
WISWESSER LINE NOTATION :
QNUYZR DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01974
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39
HS Code 2925290090

~88%

5373-87-5 structure

5373-87-5

Literature: Kharchenko; Detistov; Orlov Chemistry of Heterocyclic Compounds, 2008 , vol. 44, # 5 p. 600 - 605 Khim. Geterotsikl. Soedin., 2008 , # 5 p. 758 - 764,7

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5373-87-5 structure

5373-87-5

Literature: Miller Chemische Berichte, 1889 , vol. 22, p. 2794

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5373-87-5 structure

5373-87-5

Literature: Kinney et al. Journal of the American Chemical Society, 1933 , vol. 55, p. 3418,3421

~%

5373-87-5 structure

5373-87-5

Literature: Kinney et al. Journal of the American Chemical Society, 1933 , vol. 55, p. 3418,3421

~%

5373-87-5 structure

5373-87-5

Literature: Kinney et al. Journal of the American Chemical Society, 1933 , vol. 55, p. 3418,3421

~%

5373-87-5 structure

5373-87-5

Literature: Kovacs, Dora; Woelfling, Janos; Szabo, Nikoletta; Szecsi, Mihaly; Kovacs, Ida; Zupko, Istvan; Frank, Eva European Journal of Medicinal Chemistry, 2013 , vol. 70, p. 649 - 660

~%

5373-87-5 structure

5373-87-5

Literature: Miller Chemische Berichte, 1889 , vol. 22, p. 2794
HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%