37222-66-5

EMERGENCY OVERVIEW
Causes burns. Irritating to respiratory system. Contact with combustible material may cause fire.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion:
May cause burns to the digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Get medical aid immediately. Wash clothing before reuse.
Ingestion:
If swallowed, do NOT induce vomiting. Get medical aid immediately.
If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn. Strong oxidizer. Contact with other material may cause fire. Decomposes at high temperatures releasing oxygen which may cause an existing fire to burn more vigorously.
Extinguishing Media:
Water is a suitable extinguishing media. Do not use carbon dioxide or other gas-filled fire extinguisher; they will have no effect on decomposing persulfates.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation. Keep combustibles (wood, paper, oil, etc.,) away from spilled material.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Keep from contact with clothing and other combustible materials. Discard contaminated shoes. Do not breathe dust.
Storage:
Do not store near combustible materials. Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances. Refrigeration has been recommended. Avoid storage on wood floors.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 37222-66-5: CAS# 70693-62-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Granules
Color: white
Odor: odorless
pH: 2.0 (3% aq soln)
Vapor Pressure: Negligible.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 50 deg C (decomposes)
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature: > 50 deg C
Solubility in water: 250 g/l (20C)
Specific Gravity/Density: 1.1 - 1.4
Molecular Formula: K5H3S4O18
Molecular Weight: 614.74

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions. Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Moisture, temperatures above 50C (122F).
Incompatibilities with Other Materials:
Strong reducing agents, strong bases, combustible materials, Mixing with sodium dichloroisocyanurate or with NaCl can cause release of Cl2 gas. Mixing with cyanides can cause release of HCN gas. Mixing with heavy metal salts such as those of Co, Ni, Cu, or Mn can cause decomposition with release of O2 and heat..
Hazardous Decomposition Products:
Oxides of sulfur, oxygen.
Hazardous Polymerization: Will not occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 37222-66-5 unlisted.
CAS# 70693-62-8 unlisted.
LD50/LC50:
Not available.
Not available.
Carcinogenicity:
Potassium peroxymonosulfate sulfate (K5[HSO3(O2)]2(HSO4)(SO4)) - Not listed by ACGIH, IARC, or NTP.
Potassium peroxymonosulfate sulfate (K5[HSO3(O2)][SO3(O2)](HSO4)2) - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION
Ecotoxicity:
Fish: Rainbow trout: 53 mg/L; 96H; LC50Water flea Daphnia: 3.5 mg/L; 48H; EC50

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3260
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3260
Packing group: III

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O C
Risk Phrases:
R 34 Causes burns.
R 37 Irritating to respiratory system.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 37222-66-5: No information available.
CAS# 70693-62-8: 1
Canada
CAS# 70693-62-8 is listed on Canada's DSL List.
CAS# 37222-66-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 70693-62-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 37222-66-5 is not listed on the TSCA inventory.
It is for research and development use only.
CAS# 70693-62-8 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A