Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: Allyl glycidyl ether
Price: ￥165.0/500ml
Purity: 99.0%
Stocking Period: Inquiry
Contact: Liu jia

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Allyl glycidyl ether
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Ms Wang

Henan Tianfu Chemical Co., Ltd.
China
Product Name: TIANFU CHEM 106-92-3 Allyl glycidyl ether
Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
Purity: 99.0%
Stocking Period: Inquiry
Contact: Anson

106-92-3

106-92-3 structure

Name: Allyl glycidyl ether
Chemical Name: Allyl glycidyl ether
CAS Number: 106-92-3
Molecular Formula: C₆H₁₀O₂
Molecular Weight: 114.142
Catalog: Chemical reagent Organic reagent Ether
Create Date: 2018-02-05 08:00:00
Modify Date: 2024-01-02 08:40:39

Name	Allyl glycidyl ether
Synonyms	2-[(prop-2-en-1-yloxy)methyl]oxirane 3-allyloxy-1,2-epoxypropane Glycidyl allyl ether Allylglycide ether allyloxymethyloxirane Ally glycidyl ether EINECS 203-442-4 UNII:HDC0791894 1-Allyl-2,3-epoxypropane Sipomer AGE Allylglycidaether Ageflex AGE allyl glycidol Oxirane, 2-[(2-propen-1-yloxy)methyl]- M 560 MFCD00005143 ALLYLGLYCIDOLETHER 1-allyloxy-2,3-epoxypropane Allyl glycidyl ether ether, allyl glycidyl 2-[(Allyloxy)methyl]oxirane allyl Ether, allyl 2,3-epoxypropyl AGE

Density	1.0±0.1 g/cm3
Boiling Point	153.2±15.0 °C at 760 mmHg
Melting Point	-100 °C
Molecular Formula	C₆H₁₀O₂
Molecular Weight	114.142
Flash Point	57.2±0.0 °C
Exact Mass	114.068077
PSA	21.76000
LogP	0.78
Vapour density	3.9 (vs air)
Vapour Pressure	4.3±0.3 mmHg at 25°C
Index of Refraction	1.444
Stability	Stable. Combustible. Incompatible with strong oxidizing agents, acids, bases. May form peroxides in storage if in contact with air.
Water Solubility	50 g/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RR0875000

CHEMICAL NAME :: Oxirane, ((2-propenyloxy)methyl)-

CAS REGISTRY NUMBER :: 106-92-3

BEILSTEIN REFERENCE NO. :: 0105871

LAST UPDATED :: 199712

DATA ITEMS CITED :: 57

MOLECULAR FORMULA :: C6-H10-O2

MOLECULAR WEIGHT :: 114.16

WISWESSER LINE NOTATION :: T3OTJ B1O2U1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - changes in motor activity (specific assay) Behavioral - ataxia

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 670 ppm/8H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - corneal damage Lungs, Thorax, or Respiration - acute pulmonary edema Gastrointestinal - changes in structure or function of salivary glands

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 390 mg/kg

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Behavioral - somnolence (general depressed activity) Behavioral - ataxia

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 270 ppm/4H

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - dyspnea Gastrointestinal - changes in structure or function of salivary glands

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 2550 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 ppm/7H/10W-I

TOXIC EFFECTS :: Lungs, Thorax, or Respiration - emphysema Kidney, Ureter, Bladder - changes in bladder weight Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 200 ppm/6H/14D-I

TOXIC EFFECTS :: Sense Organs and Special Senses (Olfaction) - effect, not otherwise specified Lungs, Thorax, or Respiration - structural or functional change in trachea or bronchi Lungs, Thorax, or Respiration - other changes

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Intramuscular

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 400 mg/kg/8D-I

TOXIC EFFECTS :: Blood - changes in bone marrow (not otherwise specified) Blood - changes in leukocyte (WBC) count Nutritional and Gross Metabolic - weight loss or decreased weight gain

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 50 ppm/6H/14D-I

TOXIC EFFECTS :: Related to Chronic Data - death

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 ppm/6H/2Y-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Sense Organs and Special Senses (Olfaction) - tumors

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 10 ppm/6H/2Y-I

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Sense Organs and Special Senses (Olfaction) - tumors

TYPE OF TEST :: Sex chromosome loss and nondisjunction

MUTATION DATA

TYPE OF TEST :: Sister chromatid exchange

TEST SYSTEM :: Rodent - hamster Lung

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 249,55,1991 *** REVIEWS *** ACGIH TLV-STEL 47 mg/m3 (10 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 23 mg/m3 (5 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 5 ppm (22 mg/m3) DTLWS* "Documentation of the Threshold Limit Values for Substances in Workroom Air," Supplements. For publisher information, see 85INA8. Volume(issue)/page/year: 3,9,1971 OSHA PEL (Gen Indu):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):CL 10 ppm (45 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 ppm (22 mg/m3);STEL 10 ppm (44 mg/m3);Skin JAN 1993 OEL-AUSTRIA:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-BELGIUM:TWA 5 ppm (23 mg/m3);STEL 10 ppm (47 mg/m3);Skin JAN 1993 OEL-DENMARK:STEL 5 ppm (22 mg/m3);Skin JAN 1993 OEL-FINLAND:STEL 5 ppm (22 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 5 ppm (22 mg/m3);Skin JAN 1993 OEL-GERMANY:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 5 ppm (22 mg/m3);Skin JAN 1993 OEL-THE PHILIPPINES:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 5 ppm (22 mg/m3);STEL 10 ppm (44 mg/m3);Skin JAN 1993 OEL-THAILAND:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-TURKEY:TWA 10 ppm (45 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 5 ppm (22 mg/m3);STEL 10 ppm;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ALLYL GLYCIDYL ETHER-air:10H TWA 5 ppm;STEL 10 ppm (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 04530 No. of Facilities: 153 (estimated) No. of Industries: 9 No. of Occupations: 24 No. of Employees: 2769 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 04530 No. of Facilities: 23 (estimated) No. of Industries: 6 No. of Occupations: 11 No. of Employees: 2457 (estimated) No. of Female Employees: 29 (estimated)

Symbol	GHS02, GHS05, GHS07, GHS08
Signal Word	Danger
Hazard Statements	H226-H302-H315-H317-H318-H332-H335-H341-H351-H361f-H412
Precautionary Statements	P261-P273-P280-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xn:Harmful;
Risk Phrases	R10;R20/22;R37/38;R40;R41;R43;R52/53;R62;R68
Safety Phrases	S24/25-S26-S36/37/39-S61
RIDADR	UN 2219 3/PG 3
WGK Germany	3
RTECS	RR0875000
Packaging Group	III
Hazard Class	3
HS Code	2910900090

557-40-4

~34%

106-92-3

Literature: Oguchi, Wataru; Nishi, Makoto; Hetsugi, Yukiharu Patent: US2004/122243 A1, 2004 ; Location in patent: Page 12 ;

4638-03-3

~76%

106-92-3

Literature: Allakhverdiev; Askerov Russian Journal of Applied Chemistry, 2003 , vol. 76, # 8 p. 1280 - 1283

19701-19-0

2472-88-0

106-89-8

~63%

106-92-3

Literature: Shin-Etsu Chemical Co., Ltd. Patent: EP549335 A1, 1993 ;

107-18-6

106-89-8

106-92-3

Literature: US2314039 , ;

79-21-0

557-40-4

106-92-3

Literature: Journal of the American Chemical Society, , vol. 81, p. 3350,3352

557-40-4

2238-07-5

106-92-3

Literature: Journal of Catalysis, , vol. 228, # 1 p. 183 - 191

Precursor 7
557-40-4 4638-03-3 19701-19-0 2472-88-0
106-89-8 107-18-6 79-21-0
DownStream 10
557-40-4 148288-76-0 18044-44-5 21872-45-7
20828-26-6 20828-24-4 17980-29-9 20734-41-2
21460-36-6 826-29-9

HS Code	2910900090
Summary	2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

106-92-3	19614-99-4
95043-55-3	3814-56-0
25639-25-2	71839-56-0
26587-37-1	68334-83-8
68404-09-1	557-40-4