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109-02-4

109-02-4 structure
109-02-4 structure
Name 4-Methylmorpholine
Synonyms 4-MethylMorpholine purified by redistillation, >=
4-METHYLMORPHOLINE REAGENTPLUS(TM) 9&
Engel net impurity 65
N-Methyl morphofine
Empagliflozin Impurity 65
4-methyl-morpholin
N-ethyltetrahydropyrrole methylamine
Morpholine, N-methyl
Morpholine,4-methyl
n-Methyl morpholine
Methylmorpholine
EINECS 203-640-0
N-Me-morpholine
4-Aza-4-methyl-1-oxacyclohexane
N-MethylMorpholine purified by destillation, AcroSeal
N-METHYLMORPHOLINE (4-Methyl-morpholine)
N-Methylmorphol
N-MethylMorpholine, R
4-METHYLMORPHOLINE, FOR PROTEIN SEQUENCE ANALYSIS
N-Methyl Morpholine Extrapure
N-MethylMorpholine(Nmm)
Cetilistat Impurity 17
Methylmorpholine, 4
4-Methylmorfolin
p-Methyl morpholine
4-METHYLMORPHOLINE, REAGENTPLUS
n-methyl-morpholin
Texacat NMM
N-Methylmorpholine, purified by destillation, AcroSeal
N-Methylmorpholine,purified by destillation,AcroSeal
4-METHYLMORPHOLINE, REDISTILLED
Morpholine,N-methyl
4-MethylMorpholine , >=
Recombinant Human Non-Muscle Myosin-II Regulatory Light Chain
Dapagliflozin Impurity 52
Dapagliflozin Impurity
4-METHYLMORPHOLINE
Lupragen N105 (N-Methylmorpholine)
N-Methylmorpholine
Englenet Impurity 23
4-Methylmorpholine>
Lupragen N105
N-METHYLMORPHOLINE
LUPRAGEN(R) N
4-methylmorpholine analogue
N-METHYL MORPHOLINE Extra
1-Methylmorpholine
4-METHYL-1-OXA-4-AZACYCLOHEXANE
MFCD00006175
4-MethylMorpholine ReagentPlus(R)
4-methyl morpholine
N-Methyl morpholine
4-methylmorpholin
Density 0.9±0.1 g/cm3
Boiling Point 114.1±15.0 °C at 760 mmHg
Melting Point −66 °C(lit.)
Molecular Formula C5H11NO
Molecular Weight 101.147
Flash Point 23.9±0.0 °C
Exact Mass 101.084061
PSA 12.47000
LogP -0.33
Vapour density >1 (vs air)
Vapour Pressure 20.2±0.2 mmHg at 25°C
Index of Refraction 1.435
Water Solubility >500 g/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QE5775000
CHEMICAL NAME :
Morpholine, 4-methyl-
CAS REGISTRY NUMBER :
109-02-4
LAST UPDATED :
199710
DATA ITEMS CITED :
16
MOLECULAR FORMULA :
C5-H11-N-O
MOLECULAR WEIGHT :
101.17
WISWESSER LINE NOTATION :
T6N DOTJ A1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/30/1959
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 6/30/1959
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,888,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1960 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,85,1982
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2000 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1970 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 15,116,1979
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
25200 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. (Izdatel'stvo Meditsina, Moscow, USSR) No.1- 1961- Volume(issue)/page/year: 15,116,1979
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1350 uL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
1917 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 39(4),86,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993 OEL-SWEDEN:TWA 5 ppm (20 mg/m3);STEL 10 ppm (40 mg/m3);Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M0796 No. of Facilities: 123 (estimated) No. of Industries: 6 No. of Occupations: 8 No. of Employees: 1453 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M0796 No. of Facilities: 212 (estimated) No. of Industries: 6 No. of Occupations: 6 No. of Employees: 3141 (estimated) No. of Female Employees: 125 (estimated)
Symbol GHS02 GHS05 GHS07
GHS02, GHS05, GHS07
Signal Word Danger
Hazard Statements H225-H302-H314
Precautionary Statements P210-P280-P305 + P351 + P338-P310
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R11;R20/21/22;R34
Safety Phrases S16-S26-S36/37/39-S45-S25
RIDADR UN 2535 3/PG 2
WGK Germany 1
RTECS QE5775000
Packaging Group II
Hazard Class 3
HS Code 2934999090
HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%
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title: CAS No. 109-02-4 | Chemsrc address: https://m.chemsrc.com/en/baike/161545.html

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