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109-94-4

109-94-4 structure
109-94-4 structure
Name ethyl formate
Synonyms Ethyl forMate, standd for ,>=
ethylformate(dot)
etile(formiatodi)
Ethylformiat
Methanoicacidethylester
eginal
Ethyl formic ester
Ethyl formate >=
ForMic acid et
ETHYL FORMATE
Ethyl formate ade
Ethylformic ester
Ethyl Formate
mrowczanetylu
MFCD00003294
Methanoicacid,ethylester
EINECS 203-721-0
Ethyl ForMate [for SpectrophotoMetry]
ethyle(formiated’)
ETHYL FORMATE/FORMIC ACID ETHYL ESTER
Aethylformiat
ETHYL FORMATE BAKER ANALYZED REAGENT-500 ML
Areginal
ethylesterkyselinymravenci
Mrowczan etylu
Natural Ethyl formate
Etile(formiato di)
Ethyl methanoateFormic acid ethyl ester
FORMIC ACID ETHYL ESTER
mrowczanetylu(polish)
Ethyl methanoate
Formic ether
ETHYLFORMATE
Ethyl formate solution
EthylFormateForSynthesis
Ethylester kyseliny mravenci
ETHYL METHANOATE
Ethylformiaat
HCOOC2H5
Ethyl formate,Formic acid ethyl ester
Ethylformate
ethylformicester
ETHYL FORMATE NATURAL
Ethyl forMate SpcDry, with Moleculsieves, WaterppM (by K.F.), SpcSeal
femanumber2434
Ethyle(formiate d')
ethyl ortho-formate
formiated’ethyle
Ethyl Formate (1./ampule
EthylFormate[forSpectrophotometry]>
FORMIC ETHER
Formic Acid Ethyl Ester
Ethyl forMate SpcDry, WaterppM (by K.F.), SpcSeal
Ethyl Formate, Reagent
ethyle(formiated’)(french)
Ethyl formate, AcroSeal, Extra Dry
Ethyl forMate Extra Dry, AcroSeal
Ethyl formate, , pure
ETHYL FORMATE FCC
ethyl formiate
EthylFormate>
Formic acid ethyl
ETHYL FORMATE FOR PHARMA SYNTHESIS
Ethyl ester of formic acid
Ethyl forMat
Ethyl formate,AcroSeal,Extra Dry
ETHYL FORMATE, STANDD FOR
Density 0.9±0.1 g/cm3
Boiling Point 54.7±3.0 °C at 760 mmHg
Melting Point −80 °C(lit.)
Molecular Formula C3H6O2
Molecular Weight 74.078
Flash Point -19.4±0.0 °C
Exact Mass 74.036781
PSA 26.30000
LogP 0.30
Vapour density 2.5 (vs air)
Vapour Pressure 242.4±0.1 mmHg at 25°C
Index of Refraction 1.356
Stability Stable. Extremely flammable. May form explosive mixtures with air. Note low flash point and wide explosive limits. Incompatible with strong oxidizing agents, strong bases, strong acids, nitrates.
Water Solubility 11 g/100 mL (18 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ8400000
CHEMICAL NAME :
Formic acid, ethyl ester
CAS REGISTRY NUMBER :
109-94-4
LAST UPDATED :
199806
DATA ITEMS CITED :
35
MOLECULAR FORMULA :
C3-H6-O2
MOLECULAR WEIGHT :
74.09
WISWESSER LINE NOTATION :
VHO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 4/10/1968 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1850 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8000 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
2075 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 41,31,1972
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>20 mL/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 16,737,1978
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
1110 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Gastrointestinal - gastritis
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 2,327,1964 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
110 gm/kg/9W-I
REFERENCE :
BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 9,177,1955 *** REVIEWS *** ACGIH TLV-TWA 303 mg/m3 (100 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 100 ppm (300 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,107,1971 OSHA PEL (Gen Indu):8H TWA 100 ppm (300 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 100 ppm (300 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 100 ppm (300 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 100 ppm (300 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-BELGIUM:TWA 100 ppm (303 mg/m3) JAN 1993 OEL-DENMARK:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-FINLAND:TWA 100 ppm (300 mg/m3);STEL 150 ppm (450 mg/m3) JAN 1993 OEL-FRANCE:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-GERMANY:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-POLAND:TWA 100 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 100 ppm (300 mg/m3);STEL 200 ppm (600 mg/m3) JAN 1993 OEL-TURKEY:TWA 100 ppm (300 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 100 ppm (300 mg/m3);STEL 150 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ETHYL FORMATE-air:10H TWA 100 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 32610 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 124 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 32610 No. of Facilities: 99 (estimated) No. of Industries: 6 No. of Occupations: 19 No. of Employees: 8151 (estimated) No. of Female Employees: 1169 (estimated)
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H302 + H332-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes F:Flammable
Risk Phrases R11;R20/22;R36/37
Safety Phrases S9-S16-S24-S26-S33
RIDADR UN 1190 3/PG 2
WGK Germany 1
RTECS LQ8400000
Packaging Group II
Hazard Class 3
HS Code 2915130000
HS Code 2915120000
Summary 2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
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