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107-31-3

107-31-3 structure
107-31-3 structure

Name methyl formate
Synonyms METHYLFORMATE,HPLCADE
Methyl formate, for spectroscopy
Methyl forMate SpcDry, with Moleculsieves, WaterppM (by K.F.), SpcSeal
Methylformiaat [Dutch]
formiatedemethyle(french)
METHYL FORMATE, ABSOLUTE
METHYL FORMATE ML
Formic acid methyl ester
Methylformiat
Methyl forMate
MFCD00003291
formiatedemethyle
methylformiaate
Methyl ForMate [for SpectrophotoMetry]
Methylformiat [German]
methyle(formiatede)(french)
Methyl forMate SpcDry, WaterppM (by K.F.), SpcSeal
METHANOIC ACID-METHYL ESTER
METHYL FORMATE, FOR UV-SPECTROSCOPY
mravencanmethylnaty
Methyl forMate, extra , 1LT
Methyl ForMate, 98 Percent, SpectrophotoMetric ade
METHYL METHANOATE
Formiate de methyle [French]
Methyl forMate (C1:0) Solution
Metil
Formic acid,methyl ester
Mravencan methylnaty
Caswell No. 570
MethylFormate,Certified
methyle(formiatede)
methyl form(I)ate
METHYL FORMATE, STANDD FOR
Methylester kyseliny mravenci
Methyl formate cont. ca methanol
FORMIC ACID METHYL ESTER
Methyl ForMate [Standd Material for
Methyl methanoate
Methyl formate SuperDry, J&KSeal
Methyl formate
Methyl formate analytical standd
metil(formiatodi)
Methyl Formate [Standd Material]
METHYL FORMATE, METHYL FORMATE, METHYL FORMATE, METHYL FORMATE
Methyl forMate (C1:0)
METHYL FORMATE 1 L
HCOOCH3
METHYL FORMATE 2,5 L
Methylformiaat
EINECS 203-481-7
acid-Me
Methyl formate may cont. up to ca methanol
Methyl forMate, SuperDry, J&KSeal
Methyl formate, extra
Formiate de methyle
methyl-formate
methylesterkyselinymravenci
Ameisensuremethylester
Methyl ester of formic acid
Methyl Formate Recovered
Methyl formate spectrophotometric ade
Methyl rormate solution srandd material
Mravencan methylnaty [Czech]
Density 0.968
Boiling Point 31-33 ºC
Melting Point -100 °C
Molecular Formula C2H4O2
Molecular Weight 60.052
Flash Point -32 ºC
Exact Mass 60.021130
PSA 26.30000
LogP -0.23
Vapour density 2.1 (vs air)
Vapour Pressure 731.9±0.1 mmHg at 25°C
Index of Refraction 1.328
Stability Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
Water Solubility 300 G/L (20 ºC)

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ8925000
CHEMICAL NAME :
Formic acid, methyl ester
CAS REGISTRY NUMBER :
107-31-3
LAST UPDATED :
199712
DATA ITEMS CITED :
28
MOLECULAR FORMULA :
C2-H4-O2
MOLECULAR WEIGHT :
60.06
WISWESSER LINE NOTATION :
VHO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1622 mg/kg
REFERENCE :
IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73. For publisher information, see IOHSA5. Volume(issue)/page/year: 41,31,1972 *** REVIEWS *** ACGIH TLV-STEL 368 mg/m3 (150 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 246 mg/m3 (100 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 100 ppm (250 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,165,1971 OSHA PEL (Gen Indu):8H TWA 100 ppm (250 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 100 ppm (250 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 100 ppm (250 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 100 ppm (250 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993 OEL-AUSTRIA:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-BELGIUM:TWA 100 ppm (246 mg/m3);STEL 150 ppm (369 mg/m3) JAN 1993 OEL-DENMARK:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-FINLAND:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993 OEL-FRANCE:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-GERMANY:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 100 ppm (250 mg/m3);STEL 200 ppm JAN 1993 OEL-THE PHILIPPINES:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 100 ppm (250 mg/m3);STEL 200 ppm (500 mg/m3) JAN 1993 OEL-TURKEY:TWA 100 ppm (250 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 100 ppm (250 mg/m3);STEL 150 ppm JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO METHYL FORMATE-air:10H TWA 100 ppm;STEL 150 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 33850 No. of Facilities: 80 (estimated) No. of Industries: 6 No. of Occupations: 22 No. of Employees: 7738 (estimated) No. of Female Employees: 1402 (estimated)
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H224-H302 + H332-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes F+:Highlyflammable;Xn:Harmful;
Risk Phrases R12;R20/22;R36/37
Safety Phrases S9-S16-S24-S26-S33
RIDADR UN 1243 3/PG 1
WGK Germany 1
RTECS LQ8925000
Packaging Group I
Hazard Class 3
HS Code 2915130000
HS Code 2915120000
Summary 2915120000 salts of formic acid。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%
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