13478-18-7

13478-18-7 structure
13478-18-7 structure

Name molybdenum trichloride
Synonyms ybdenum(III) chL
Molybdenum(III) chloride, trace
MFCD00014214
MOLYBDENUM CHLORIDE
MOLYBDENUM (III) CHLORIDE
MOLYBDENUM TRICHLORIDE
molybdenumchloride(mocl3)
MolybdenuM(III) chloride trace Metals basis
MOLYBDENUM CHLORIDE (III)
MOLYBDENUM (III) CHLORIDE, MOLYBDENUM (III) CHLORIDE, MOLYBDENUM (III) CHLORIDE
trichloromolybdenum
Molybdenum(III)chloride
Molybdenum(III)chloride(-Mo)
MoCl3
EINECS 236-775-9
Molybdenum(3+) trichloride
MOLYBDENUM (III) CHL
MOLYBDENUM(III) CHLORIDE
Einecs -9
trichloridomolybdenum
Density 3.58 g/mL at 25 °C(lit.)
Melting Point 1027°C
Molecular Formula Cl3Mo
Molecular Weight 202.299
Exact Mass 202.811966
LogP 2.06850
Appearance Powder | Dark red
Vapour Pressure 33900mmHg at 25°C
Water Solubility H2O: insoluble(lit.) | Soluble in nitric acid and sulfuric acid. Insoluble in water and dilute hydrochloric acid. Slightly soluble in ethanol and diethyl ether.

Section 1: Product Identification
Chemical Name:Molybdenum(III) chloride (99.5%-Mo)
CAS Registry Number:13478-18-7
Formula:MoCl3
EINECS Number:236-775-9
Chemical Family:metal halide
Synonym:Molybdenum trichloride

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13478-18-7100%0.5mg/m35mg/m3

Section 3: Hazards Identification
Emergency Overview:Corrosive to skin, eyes and respiratory tract. Inhalation of dust leads to burning of the respiratory tract.
Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
Eye Contact:Corrosive to the eyes.
Skin Contact:Causes burns to the skin.
Inhalation:Inhalation of dust leads to chemical burns of the respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
Acute Health Affects:Corrosive to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andnone
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be neutralized with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
Spill and Leak Procedures:Large spills in areas not adequately ventilated will require an evacuation of site. Emergency response teams
will require self-contained breathing apparatus.

SECTION 7: Handling and Storage
Handling and Storage:Store material in a tightly sealed container under an inert atmosphere of nitrogen or argon.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing gloves. Consult glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:-100 mesh purple xtl.
Molecular Weight:202.32
Melting Point:dec.
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:3.59
Odor:none
Solubility in Water:reacts with water

SECTION 10: Stability and Reactivity
Stability:air sensitive, moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:active metals
Decomposition Products:none

SECTION 11: Toxicological Information
RTECS Data:Oral (insect-Drosophila melanogaster); Specific locus test: 10nmol/L.
Carcinogenic Effects:no data
Mutagenic Effects:Mutagen
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Corrosive solids, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 1759
Shipping Name (IATA):Corrosive solid, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 1759

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QA4681400
CHEMICAL NAME :
Molybdenum chloride (MoCl3)
CAS REGISTRY NUMBER :
13478-18-7
LAST UPDATED :
199707
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
Cl3-Mo
MOLECULAR WEIGHT :
202.29

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :
Insect - Drosophila melanogaster
DOSE/DURATION :
10 mmol/L
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 320,133,1994
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26;S37/S39
RIDADR UN3260
WGK Germany 3
RTECS QA4681400
Packaging Group III
Hazard Class 8

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13478-18-7 structure

13478-18-7

Literature: Ullmanns Encykl. Tech. Chem. 4th Ed., , vol. 17, p. 23 - 50 Mo: SVol.A3, 2.4.6.2, page 62 - 63

~%

13478-18-7 structure

13478-18-7

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 71, p. 453 - 453

~%

13478-18-7 structure

13478-18-7

Literature: Mo: SVol.A3, 2.7.27, page 182 - 183

~%

13478-18-7 structure

13478-18-7

Literature: Chemiker-Zeitung, , vol. 12, p. 5 - 5 Mo: MVol., 56, page 162 - 164

~%

13478-18-7 structure

13478-18-7

Literature: Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1197 - 1198

~%

13478-18-7 structure

13478-18-7

Literature: European Journal of Inorganic Chemistry, , # 10 p. 2699 - 2703
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