460092-03-9

460092-03-9 structure
460092-03-9 structure
  • Name: trihexyl(tetradecyl)phosphonium bis(trifluoromethylsulfonyl)imide
  • Chemical Name: bis(trifluoromethylsulfonyl)azanide,trihexyl(tetradecyl)phosphanium
  • CAS Number: 460092-03-9
  • Molecular Formula: C34H68F6NO4PS2
  • Molecular Weight: 764.00200
  • Catalog: Chemical reagent Organic reagent Ionic liquid
  • Create Date: 2018-12-28 18:04:30
  • Modify Date: 2024-01-02 16:29:20
  • Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide [P6,6,6,14][Ntf2] is an ionic liquid generally used in biosensorselectrodeposition,and synthetic chemistry applications.

Name bis(trifluoromethylsulfonyl)azanide,trihexyl(tetradecyl)phosphanium
Synonyms tetradecyltrihexylphosphonium NTf2
Tetradecyltrihexylphosphonium bis(trifluoromethylsulfonyl)amide
[PR4][Tf2N]
MFCD04117695
Trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)amide
[P6,6,6,14][NTf2]
[TDTHP][NTf2]
[THTDP][NTf2]
Density 1.07 g/mL at 20ºC(lit.)
Molecular Formula C34H68F6NO4PS2
Molecular Weight 764.00200
Flash Point 52ºC
Exact Mass 763.42300
PSA 98.63000
LogP 15.66690
Appearance liquid | colorless

Section 1: Product Identification
Chemical Name:Trihexyl(tetradecyl)phosphonium bis(trifluoromethanesulfonyl)amide, min. 97% CYPHOS IL 109
CAS Registry Number:460092-03-9
Formula:[(C6H13)3(C14H29)P]+[(CF3SO2)N]-
EINECS Number:none
Chemical Family:organophosphine compound
Synonym:CYPHOSIL 109

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound460092-03-9100%2.5mg(F)/m32.5mg(F)/m3

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, skin
Eye Contact:Causes mild to moderate irritation to the eyes.
Skin Contact:Causes mild to moderate irritation of the skin.
Inhalation:As a liquid aerosol, irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Product contains fluorine which, under certain conditions of use, decomposition or metabolism, may generate
Chronic Health Affects:fluoride ion causing nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth
structure and kidney and liver damage.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam.
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Keep container tightly closed. Store in a cool, dry place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:colorless liq.
Molecular Weight:764
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, phosphorous pentoxide, sulfur and nitrogen oxides, hydrofluoric acid and organic fumes.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes C
Risk Phrases R10;R22;R34
Safety Phrases S26;S45;S36/S37/S39
RIDADR UN 2920 8/PG 2
WGK Germany 3