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2642-71-9

2642-71-9 structure
2642-71-9 structure
Name azinphos-ethyl
Synonyms Dithiophosphate de O,O-diéthyle et de S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)méthyle]
azinfos-ethyl
Gutex
triazothion
Azinphos-ethyl
Gusathion H & K
Athyl-gusathion
O,O-Diethyl S-((4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl) phosphorodithioate (9CI)
Gusathion
Ethyl-Gusathion
Azinphosethyl
O,O-Diethyl-S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl]dithiophosphat
Crysthion
Azinphos-ethyl PESTANAL(R),analytical standard
EINECS 220-147-6
O,O-Diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] phosphorodithioate
Azinophos-ethyl
Bionex
S-3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl O,O-diethyl phosphorodithioate
Ethyl azinphos
Azinphos ethyl
MFCD00055539
O,O-diethyl S-<(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl> phosphorodithioate
O,O-diethyl-S(3,4-dihydro-4-oxobenzo<d><1,2,3>triazin-3-yl-methyl)phosphorodithioate
Phosphorodithioic acid, O,O-diethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] ester
Azinos
3-(diethoxyphosphinothioylsulfanylmethyl)-1,2,3-benzotriazin-4-one
Density 1.4±0.1 g/cm3
Boiling Point 444.7±55.0 °C at 760 mmHg
Melting Point 53ºC
Molecular Formula C12H16N3O3PS2
Molecular Weight 345.378
Flash Point 222.7±31.5 °C
Exact Mass 345.037079
PSA 133.44000
LogP 3.61
Vapour Pressure 0.0±1.1 mmHg at 25°C
Index of Refraction 1.651

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TD8400000
CHEMICAL NAME :
Phosphorodithioic acid, O,O-diethyl ester, S-ester with 3-(mercaptomethyl)- 1,2,3-benzotriazin-4(3H)-one
CAS REGISTRY NUMBER :
2642-71-9
BEILSTEIN REFERENCE NO. :
0297468
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C12-H16-N3-O3-P-S2
MOLECULAR WEIGHT :
345.40
WISWESSER LINE NOTATION :
T66 BNNNVJ D1SPS&O2&O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ARSIM* Agricultural Research Service, USDA Information Memorandum. (Beltsville, MD 20705) Volume(issue)/page/year: 20,2,1966
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
390 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GYAV "Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen," 2nd ed., Klimmer, O.R., Hattingen, Fed. Rep. Ger., Hundt-Verlag, 1971 Volume(issue)/page/year: -,16,1971
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,24,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
7500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,24,1973
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
12 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,45,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
34400 ug/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 11,49,1967 *** REVIEWS *** TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 51,123,1974 TOXICOLOGY REVIEW RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 63,1,1976
Symbol GHS06 GHS09
GHS06, GHS09
Signal Word Danger
Hazard Statements H300-H311-H410
Precautionary Statements P273-P280-P301 + P310 + P330-P302 + P352 + P312-P391-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard Codes T+: Very toxic;N: Dangerous for the environment;
Risk Phrases 24-28-50/53
Safety Phrases S28-S36/37-S45-S60-S61
RIDADR 2783
RTECS TD8400000
Packaging Group II
Hazard Class 6.1(a)

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