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356-27-4

356-27-4 structure
356-27-4 structure

Name ethyl 2,2,3,3,4,4,4-heptafluorobutanoate
Synonyms Ethyl heptafluorobutanoate
Ethyl heptafluorobutyrate
Perfluorobutyric Acid Ethyl Ester
2,2,3,3,4,4,4-heptafluoro-butyric acid ethyl ester
EINECS 206-602-1
ethyl perfluoroisobutyrate
Butanoic acid,heptafluoro-,ethyl ester
BUTYRIC ACID,HEPTAFLUORO-,ETHYL ESTER
Ethyl Perfluorobutyrate
Heptafluorobutyric acid ethyl ester
ethyl 2,2,3,3,4,4,4-heptafluorobutyrate
Ethyl perfluorobutanoate
MFCD00000434
Density 1.396 g/mL at 25 °C(lit.)
Boiling Point 95-98°C
Molecular Formula C6H5F7O2
Molecular Weight 242.09200
Flash Point 58 °F
Exact Mass 242.01800
PSA 26.30000
LogP 2.38240
Index of Refraction n20/D 1.302(lit.)
Storage condition Flammables area

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ET4200000
CHEMICAL NAME :
Butyric acid, heptafluoro-, ethyl ester
CAS REGISTRY NUMBER :
356-27-4
BEILSTEIN REFERENCE NO. :
1794634
LAST UPDATED :
199709
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C6-H5-F7-O2
MOLECULAR WEIGHT :
242.11
WISWESSER LINE NOTATION :
FXFFXFFXFFVO2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
250 mg/kg
TOXIC EFFECTS :
Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - dyspnea Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 2,299,1950 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4670 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 28 (estimated)
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H315-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F: Flammable;Xi: Irritant;
Risk Phrases R10
Safety Phrases S16-S26-S33-S36
RIDADR UN 3272 3/PG 2
WGK Germany 3
RTECS ET4200000
Packaging Group II
Hazard Class 3
HS Code 2915900090

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356-27-4 structure

356-27-4

Literature: Journal of the Chemical Society, , p. 2789,2791 Journal of Organic Chemistry, , vol. 23, p. 476 Journal of the American Chemical Society, , vol. 75, p. 992 Journal of the American Chemical Society, , vol. 77, p. 4164,4167

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356-27-4 structure

356-27-4

Literature: Journal of the American Chemical Society, , vol. 79, p. 4759

~94%

356-27-4 structure

356-27-4

Literature: Avetisyan; Cherstkov; Tumanskii; Sterlin Russian Chemical Bulletin, 1998 , vol. 47, # 12 p. 2429 - 2433

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356-27-4 structure

356-27-4

Literature: Zh. Vses. Khim. Obshchestva, , vol. 26, p. 34718 C.A., , vol. 95, p. 168460

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356-27-4 structure

356-27-4

Literature: Russian Chemical Bulletin, , vol. 47, # 12 p. 2429 - 2433
HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%