312696-25-6

312696-25-6 structure
312696-25-6 structure
  • Name: TRIS(ISOPROPYLCYCLOPENTADIENYL)TERBIUM
  • Chemical Name: 2-propan-2-ylcyclopenta-1,3-diene,terbium(3+)
  • CAS Number: 312696-25-6
  • Molecular Formula: C24H33Tb
  • Molecular Weight: 480.44400
  • Create Date: 2018-12-28 19:54:15
  • Modify Date: 2024-01-29 14:39:24

Name 2-propan-2-ylcyclopenta-1,3-diene,terbium(3+)
Synonyms Tris(isopropylcyclopentadienyl)terbium
MFCD00798537
Tris(isopropylcyclopentadienyl)terbium(III)
Terbium,tris[(1,2,3,4,5-h)-1-(1-methylethyl)-2,4-cyclopentadien-1-yl]
Molecular Formula C24H33Tb
Molecular Weight 480.44400
Flash Point 76ºC
Exact Mass 480.18400
LogP 7.42920

Section 1: Product Identification
Chemical Name:Tris(i-propylcyclopentadienyl)terbium (99.9%-Tb) (REO)
CAS Registry Number:312696-25-6
Formula:(C3H7C5H4)3Tb
EINECS Number:none
Chemical Family:metallocene
Synonym:tris(1-isopropyl-eta5-2,4-cyclopentadien-1-yl)terbium

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound312696-25-6100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and mucous membranes.
Primary Routes of Exposure:Ingestion, eyes
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this product may emit toxic and irritating organic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handle and store the material under an inert atmosphere of nitrogen or argon. Keep away from air and
Handling and Storage:
moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:yellow solid
Molecular Weight:480.45
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to air, heat sources, ignition sources
Incompatibility:Air, oxidizing agents, halogens, protic reagents
Decomposition Products:terbium oxide, carbon monoxide and carbon dioxide.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Safety Phrases S16-S33
RIDADR UN3181
Packaging Group III
Hazard Class 4.1