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51338-27-3

51338-27-3 structure
51338-27-3 structure
  • Name: DICLOFOP-METHYL
  • Chemical Name: diclofop-methyl
  • CAS Number: 51338-27-3
  • Molecular Formula: C16H14Cl2O4
  • Molecular Weight: 341.186
  • Catalog: Chemical pesticide herbicide Other herbicides
  • Create Date: 2018-07-11 22:41:36
  • Modify Date: 2024-01-06 11:39:07
  • Diclofop-methyl, a common post-emergence herbicide, is widely used in agriculture production. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast[1][2].

Name diclofop-methyl
Synonyms Propanoic acid, 2-[4-(2,4-dichlorophenoxy)phenoxy]-, methyl ester
DICLOFOP-METHYL
Hoelon
2-[4-(2,4-Dichlorophenoxy)phenoxy]propanoic Acid Methyl Ester
Hoe-grass
Illoxan
Diclofop methyl ester
MFCD00128052
Diclofop, methyl ester
EINECS 257-141-8
diclofop methyl
Methyl 2-[4-(2,4-Dichlorophenoxy)phenoxy]propionate
rac-methyl (2R)-2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
Hoegrass
methyl (RS)-2-[4-(2,4-dichlorophenoxy)phenoxy]propionate
Methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate
METHYL (RS)-2-(4-(2,4-DICHLOROPHENOXY)PHENOXY)PROPIONATE
Description Diclofop-methyl, a common post-emergence herbicide, is widely used in agriculture production. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast[1][2].
Related Catalog
In Vitro Diclofop-methyl (1 micromolar) significantly reduced the steady-state H(+) gradient generated in the presence of ATP[1].
References

[1]. Ratterman DM, et al. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast. Plant Physiol. 1989;91(2):756-765.

[2]. Li X, et al. The interactive effects of diclofop-methyl and silver nanoparticles on Arabidopsis thaliana: Growth, photosynthesis and antioxidant system. Environ Pollut. 2018;232:212-219.

Density 1.3±0.1 g/cm3
Boiling Point 408.0±45.0 °C at 760 mmHg
Melting Point 39-41°C
Molecular Formula C16H14Cl2O4
Molecular Weight 341.186
Flash Point 150.3±27.7 °C
Exact Mass 340.026917
PSA 44.76000
LogP 4.24
Vapour Pressure 0.0±1.0 mmHg at 25°C
Index of Refraction 1.562
Water Solubility 0.005 g/100 mL

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UF1180000
CHEMICAL NAME :
Propionic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester
CAS REGISTRY NUMBER :
51338-27-3
LAST UPDATED :
199612
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C16-H14-Cl2-O4
MOLECULAR WEIGHT :
341.20
WISWESSER LINE NOTATION :
GR CG DOR DOY1&VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
512 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C165,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
8300 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
586 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ZDBEA9 Zdravookhranenie Belorussii. Public Health Service of White Russia. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1955- Volume(issue)/page/year: (3),29,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
1600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
>10 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,262,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
672 mg/kg/4W-C
TOXIC EFFECTS :
Liver - changes in liver weight Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)
REFERENCE :
BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 40,153,1988 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989
Symbol GHS07 GHS09
GHS07, GHS09
Signal Word Warning
Hazard Statements H302-H317-H410
Precautionary Statements P273-P280-P501
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn:Harmful;N:Dangerousfortheenvironment;
Risk Phrases R22;R43;R50/53
Safety Phrases S24-S37-S60-S61
RIDADR UN 3077
RTECS UF1180000
HS Code 2918990025

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51338-27-3 structure

51338-27-3

Literature: US4531969 A1, ;

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51338-27-3 structure

51338-27-3

Literature: Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 35, # 3 p. 366 - 371
HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%