DICLOFOP-METHYL

Modify Date: 2024-01-06 11:39:07

DICLOFOP-METHYL structure	Common Name	DICLOFOP-METHYL
	CAS Number	51338-27-3	Molecular Weight	341.186
	Density	1.3±0.1 g/cm3	Boiling Point	408.0±45.0 °C at 760 mmHg
	Molecular Formula	C₁₆H₁₄Cl₂O₄	Melting Point	39-41°C
	MSDS	Chinese USA	Flash Point	150.3±27.7 °C
	Symbol	GHS07, GHS09	Signal Word	Warning

Use of DICLOFOP-METHYL

Diclofop-methyl, a common post-emergence herbicide, is widely used in agriculture production. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast[1][2].

Name	diclofop-methyl
Synonym	More Synonyms

Description	Diclofop-methyl, a common post-emergence herbicide, is widely used in agriculture production. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast[1][2].
Related Catalog	Research Areas >> Others Signaling Pathways >> Others >> Others
In Vitro	Diclofop-methyl (1 micromolar) significantly reduced the steady-state H(+) gradient generated in the presence of ATP[1].
References	[1]. Ratterman DM, et al. Diclofop-methyl increases the proton permeability of isolated oat-root tonoplast. Plant Physiol. 1989;91(2):756-765. [2]. Li X, et al. The interactive effects of diclofop-methyl and silver nanoparticles on Arabidopsis thaliana: Growth, photosynthesis and antioxidant system. Environ Pollut. 2018;232:212-219.

Density	1.3±0.1 g/cm3
Boiling Point	408.0±45.0 °C at 760 mmHg
Melting Point	39-41°C
Molecular Formula	C₁₆H₁₄Cl₂O₄
Molecular Weight	341.186
Flash Point	150.3±27.7 °C
Exact Mass	340.026917
PSA	44.76000
LogP	4.24
Vapour Pressure	0.0±1.0 mmHg at 25°C
Index of Refraction	1.562
Water Solubility	0.005 g/100 mL

DICLOFOP-METHYL MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UF1180000

CHEMICAL NAME :: Propionic acid, 2-(4-(2,4-dichlorophenoxy)phenoxy)-, methyl ester

CAS REGISTRY NUMBER :: 51338-27-3

LAST UPDATED :: 199612

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C16-H14-Cl2-O4

MOLECULAR WEIGHT :: 341.20

WISWESSER LINE NOTATION :: GR CG DOR DOY1&VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 512 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C165,1991

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 8300 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 586 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: ZDBEA9 Zdravookhranenie Belorussii. Public Health Service of White Russia. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1955- Volume(issue)/page/year: (3),29,1984

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 85JFAN "Agrochemicals Handbook," with updates, Hartley, D., and H. Kidd, eds., Nottingham, Royal Soc. of Chemistry, 1983-86 Volume(issue)/page/year: A138,1983

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - quail

DOSE/DURATION :: >10 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,262,1991 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 672 mg/kg/4W-C

TOXIC EFFECTS :: Liver - changes in liver weight Blood - other changes Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.)

REFERENCE :: BECTA6 Bulletin of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1966- Volume(issue)/page/year: 40,153,1988 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Symbol	GHS07, GHS09
Signal Word	Warning
Hazard Statements	H302-H317-H410
Precautionary Statements	P273-P280-P501
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes	Xn:Harmful;N:Dangerousfortheenvironment;
Risk Phrases	R22;R43;R50/53
Safety Phrases	S24-S37-S60-S61
RIDADR	UN 3077
RTECS	UF1180000
HS Code	2918990025

4-(2,4-Dichloro...

CAS#:40843-73-0

methyl 2-(4-met...

CAS#:66648-29-1

DICLOFOP-METHYL

CAS#:51338-27-3

Literature: US4531969 A1, ;

Methyl 2-bromop...

CAS#:5445-17-0

4-(2,4-Dichloro...

CAS#:40843-73-0

~91%

DICLOFOP-METHYL

CAS#:51338-27-3

Literature: Zeitschrift fuer Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, , vol. 35, # 3 p. 366 - 371

Precursor 3
CAS#:40843-73-0 4-(2,4-Dichloro... CAS#:66648-29-1 methyl 2-(4-met... CAS#:5445-17-0 Methyl 2-bromop...
DownStream 2
CAS#:40843-25-2 Diclofop CAS#:75021-71-5 S-(-)-diclofop

HS Code	2918990090
Summary	2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Characterisation of target-site resistance to ACCase-inhibiting herbicides in the weed Alopecurus myosuroides (black-grass).

Pest Manag. Sci. 59(2) , 190-201, (2003)

Resistance to aryloxyphenoxypropionate (AOPP), cyclohexanedione (CHD) and phenylurea herbicides was determined in UK populations of Alopecurus myosuroides Huds. Two populations (Oxford AA1, Notts. A1)...

Genetic control of a cytochrome P450 metabolism-based herbicide resistance mechanism in Lolium rigidum.

Heredity (Edinb.) 106(5) , 817-24, (2011)

The dynamics of herbicide resistance evolution in plants are influenced by many factors, especially the biochemical and genetic basis of resistance. Herbicide resistance can be endowed by enhanced rat...

Recurrent selection with reduced herbicide rates results in the rapid evolution of herbicide resistance in Lolium rigidum.

Theor. Appl. Genet. 110(6) , 1154-66, (2005)

There has been much debate regarding the potential for reduced rates of herbicide application to accelerate evolution of herbicide resistance. We report a series of experiments that demonstrate the po...

Propanoic acid, 2-[4-(2,4-dichlorophenoxy)phenoxy]-, methyl ester

DICLOFOP-METHYL

Hoelon

2-[4-(2,4-Dichlorophenoxy)phenoxy]propanoic Acid Methyl Ester

Hoe-grass

Illoxan

Diclofop methyl ester

MFCD00128052

Diclofop, methyl ester

EINECS 257-141-8

diclofop methyl

Methyl 2-[4-(2,4-Dichlorophenoxy)phenoxy]propionate

rac-methyl (2R)-2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate

Hoegrass

methyl (RS)-2-[4-(2,4-dichlorophenoxy)phenoxy]propionate

Methyl 2-[4-(2,4-dichlorophenoxy)phenoxy]propanoate

METHYL (RS)-2-(4-(2,4-DICHLOROPHENOXY)PHENOXY)PROPIONATE

Shanghai Jizhi Biochemical Technology Co., Ltd
China
Product Name: DICLOFOP-METHYL
Price: ￥798.0/250mg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Liu jia

DC Chemicals Limited
China
Product Name: Diclofop-methyl
Price: $Inquiry/250mg $Inquiry/100mg $Inquiry/1g
Purity: 98.0%
Stocking Period: 3 Day
Contact: Tony Cao

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Diclofop-methyl
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Stocking Period: Inquiry
Contact: Ms Wang

Zhejiang Hangyu API Co., Ltd
China
Product Name: Diclofop-methyl
Price: ￥Inquiry/1kg
Purity: 99.5%
Stocking Period: Inquiry
Contact: Vinnie

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