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132682-77-0

132682-77-0 structure
132682-77-0 structure

Name 2-Diphenylphosphino-6-methylpyridine
Synonyms (6-methylpyridin-2-yl)-diphenylphosphane
Boiling Point 390.3ºC at 760 mmHg
Melting Point 81-83ºC
Molecular Formula C18H16NP
Molecular Weight 277.30000
Flash Point 189.9ºC
Exact Mass 277.10200
PSA 26.48000
LogP 3.14820
Appearance crystal | white to off-white
Vapour Pressure 6.01E-06mmHg at 25°C

Section 1: Product Identification
Chemical Name:2-Diphenylphosphino-6-methylpyridine, 98%
CAS Registry Number:132682-77-0
Formula:C18H16NP
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:2-Diphenylphosphanyl-6-methyl-pyridine

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound132682-77-0100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Inhalation, skin, eyes
Eye Contact:Causes moderate irritation of the eyes.
Skin Contact:Causes mild to moderate irritation of the skin.
Inhalation:Inhalation causes irritation to the nose, mucous membranes and respiratory tract.
Ingestion:No specific information is available on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam.
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white to off-white xtl.
Molecular Weight:277.3
Melting Point:81-83 °
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases 26-36/37/39
HS Code 29333990

~90%

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Literature: Grotjahn, Douglas B.; Lev, Daniel A. Journal of the American Chemical Society, 2004 , vol. 126, # 39 p. 12232 - 12233

~87%

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132682-77-0

Literature: Li, Yuehui; Lu, Liang-Qiu; Das, Shoubhik; Pisiewicz, Sabine; Junge, Kathrin; Beller, Matthias Journal of the American Chemical Society, 2012 , vol. 134, # 44 p. 18325 - 18329

~77%

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132682-77-0

Literature: Shell Oil Company Patent: US5166411 A1, 1992 ;

~91%

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Literature: Li, Yuehui; Das, Shoubhik; Zhou, Shaolin; Junge, Kathrin; Beller, Matthias Journal of the American Chemical Society, 2012 , vol. 134, # 23 p. 9727 - 9732

~66%

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Literature: Scrivanti; Beghetto; Matteoli Advanced Synthesis and Catalysis, 2002 , vol. 344, # 5 p. 543 - 547

~31%

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132682-77-0

Literature: Chemistry - A European Journal, , vol. 18, # 31 p. 9622 - 9627

~%

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132682-77-0

Literature: Inorganic Chemistry, , vol. 52, # 5 p. 2292 - 2305

~%

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132682-77-0

Literature: Inorganic Chemistry, , vol. 52, # 5 p. 2292 - 2305