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1313-22-0

1313-22-0 structure
1313-22-0 structure

Name Manganese(II) Selenide
Synonyms MANGANESE SELENIDE
EINECS 215-203-1
MFCD00049486
manganese(II) selenide
Density 5,45 g/cm3
Melting Point 1460°C
Molecular Formula HMnSe
Molecular Weight 134.90600
Exact Mass 135.86200
Appearance crystal | black
Water Solubility insoluble H2O [CRC10]

Section 1: Product Identification
Chemical Name:Manganese (II) selenide (99.9%-Mn)
CAS Registry Number:1313-22-0
Formula:MnSe
EINECS Number:215-203-1
Chemical Family:metal chalcogenide
Synonym:None

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound1313-22-0100%0.2mg/m3 as Mn5mg/m3 (as Mn)

Section 3: Hazards Identification
May be irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Some compounds of
Emergency Overview:
manganese affect the central nervous system. Selenium causes shortness of breath, chills and headache.
Primary Routes of Exposure:Inhalation, ingestion.
Eye Contact:May cause slight to mild irritation of the eyes.
Skin Contact:May cause slight to mild irritation of the skin.
Dust may be irritating to the nose, mucous membranes and respiratory tract and cause chronic health
Inhalation:
problems.
Ingestion:No information available on the physiological effects of ingestion.
Acute Health Affects:May be irritating to skin, eyes and respiratory tract.
Prolonged exposure to manganese containing dust may produce manganese pneumonitis and manganese
Chronic Health Affects:poisoning. Symptoms include sleepiness, weakness and emotional disturbances. Equivocal studies have
shown manganese may decrease fertility in men.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in
Inhalation:
breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder.
If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic manganese oxide fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: Non-flammable material. No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store the material in a sealed container. Keep away from heat and moisture.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:-20 mesh black xtl
Molecular Weight:133.9
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:not determined
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization.
Conditions to Avoid:none
Incompatibility:oxidizing agents
Decomposition Products:selenium oxide and manganese oxide

SECTION 11: Toxicological Information
RTECS Data:No information available in RTECS.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available.

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound: See category codes N450 and N725 for reporting
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes T+
Risk Phrases 23/25-33-50/53
Safety Phrases 20/21-28-45
RIDADR UN 3283
Packaging Group II
Hazard Class 6.1