Name | benzyl(triethyl)azanium,carbonochloridate |
---|---|
Synonyms |
benzyltriethylammonium chloroformate
MFCD01318311 |
Melting Point | 87-91ºC |
---|---|
Molecular Formula | C13H22ClCrNO3 |
Molecular Weight | 327.76800 |
Exact Mass | 327.06900 |
PSA | 57.20000 |
LogP | 3.39620 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 43 8 49 50/53 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
May cause sensitization by skin contact. Contact with combustible material may cause fire. May cause cancer by inhalation. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: May cause respiratory tract irritation. May be harmful if inhaled. Chronic: May cause cancer in humans. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid immediately. Wash mouth out with water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Oxidizer. Greatly increases the burning rate of combustible materials. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 106542-73-8: United Kingdom, WEL - TWA: (listed as chromium (vi) compounds): 0 mg/m3 TWA (as Cr) United Kingdom, WEL - STEL: (listed as chromium (vi) compounds): mg/m3 STEL (as Cr) Belgium - TWA: (listed as chromium (vi) compounds- water soluble) 0.05 mg/m3 VLE (as Cr) France - VME: (listed as chromium (vi) compounds): 0.05 mg/m3 VME Cr) Germany: (listed as chromium (vi) compounds): 0.05 mg/m3 VME (as Japan: (listed as chromium (vi) compounds): 0.05 mg/m3 OEL (as Cr 0.01 mg/m3 OEL (certain compounds, as Cr) Malaysia: (listed as chromium (vi) compounds- water soluble): 0.0 mg/m3 TWA (as Cr) Netherlands: (listed as chromium (vi) compounds- water soluble): mg/m3 STEL Netherlands: (listed as chromium (vi) compounds- water soluble): 0.025 mg/m3 MAC Spain: (listed as chromium (vi) compounds- water soluble): 0.05 m VLA-ED (as Cr) Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Crystals Color: yellow - orange - yellow-orange Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 87 - 91 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Soluble. Specific Gravity/Density: Molecular Formula: C13H22ClCrNO3 Molecular Weight: 327.77 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Incompatible materials, dust generation, combustible materials. Incompatibilities with Other Materials: Alcohols, strong reducing agents, strong acids. Hazardous Decomposition Products: Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 106542-73-8 unlisted. LD50/LC50: Not available. Carcinogenicity: Benzyltriethylammonium chlorochromate - California: carcinogen, initial date 2/27/87 (listed as Chromium (VI) NTP: Known carcinogen (listed as Chromium (VI) compounds). IARC: Group 1 carcinogen (listed as Chromium (VI) compounds). Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: OXIDIZING SOLID, N.O.S.* Hazard Class: 5.1 UN Number: 1479 Packing Group: II IMO Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing Group: II RID/ADR Shipping Name: OXIDIZING SOLID, N.O.S. Hazard Class: 5.1 UN Number: 1479 Packing group: II Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: T O N Risk Phrases: R 49 May cause cancer by inhalation. R 43 May cause sensitization by skin contact. R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 8 Contact with combustible material may cause fire. Safety Phrases: S 53 Avoid exposure - obtain special instructions before use. S 17 Keep away from combustible material. S 24 Avoid contact with skin. S 37 Wear suitable gloves. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S 60 This material and its container must be disposed of as hazardous waste. S 61 Avoid release to the environment. Refer to special instructions/safety data sheets. WGK (Water Danger/Protection) CAS# 106542-73-8: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 106542-73-8 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 106542-73-8 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |