Name | 5-(2-chloroethyl)-2H-tetrazole |
---|---|
Synonyms |
5-(2-chloroethyl)-2H-1,2,3,4-tetrazole
5-(2-Chloroethyl)-1H-tetrazole 5-(2-Chloroethyl)Tetrazole 5-(2-chloro-ethyl)-1(2)H-tetrazole MFCD00123349 5-(2-chloroethyl)-2H-1,2,3,4-tetraazole 5-Chloroethyl-1H-tetrazole |
Density | 1.446g/cm3 |
---|---|
Boiling Point | 298.4ºC at 760mmHg |
Melting Point | 103ºC |
Molecular Formula | C3H5ClN4 |
Molecular Weight | 132.55200 |
Flash Point | 162.4ºC |
Exact Mass | 132.02000 |
PSA | 54.46000 |
Vapour Pressure | 0.00128mmHg at 25°C |
Index of Refraction | 1.553 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 11 34 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Highly flammable. Causes burns. Potential Health Effects Eye: Causes eye burns. Skin: Causes skin burns. Ingestion: Causes gastrointestinal tract burns. Inhalation: Causes chemical burns to the respiratory tract. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Do not induce vomiting. Get medical aid immediately. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable solid. Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - HANDLING and STORAGE Handling: Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Storage: Store in a cool, dry place. Store in a tightly closed container. Flammables-area. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels. Exposure Limits CAS# 18755-46-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: None reported. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 103 - 105 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C3H5ClN4 Molecular Weight: 133 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials, ignition sources. Incompatibilities with Other Materials: Strong oxidizing agents, bases. Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, oxides of nitrogen, carbon dioxide. Hazardous Polymerization: Has not been reported. Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 18755-46-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 5-(2-Chloroethyl)-1H-1,2,3,4-tetraazole - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S.* Hazard Class: 4.1 (8) UN Number: 2925 Packing Group: III IMO Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. Hazard Class: 4.1 (8) UN Number: 2925 Packing Group: III RID/ADR Shipping Name: FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. Hazard Class: 4.1 (8) UN Number: 2925 Packing group: III Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: F C Risk Phrases: R 11 Highly flammable. R 34 Causes burns. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). WGK (Water Danger/Protection) CAS# 18755-46-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 18755-46-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 18755-46-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | F:Highlyflammable;C:Corrosive; |
---|---|
Risk Phrases | R11;R34 |
Safety Phrases | S16-S26-S36/37/39-S45 |
HS Code | 2933990090 |
~87% 18755-46-9 |
Literature: Huff, Bret E.; Staszak, Michael A. Tetrahedron Letters, 1993 , vol. 34, # 50 p. 8011 - 8014 |
Precursor 1 | |
---|---|
DownStream 1 | |
HS Code | 2933990090 |
---|---|
Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |