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123-77-3

123-77-3 structure
123-77-3 structure
Name Azodicarbonamide
Synonyms FoaMer ADC
(cbaMoyliMino)urea
1,1’-azobiscbamide
1,1'-Azodiformamide
celogenaz199
celosenaz
kempore
azodicboamide
Diazene-1,2-dicarboxamide
AZODICBONAMIDE, (HPLC) FCC
##DISCONTINUED## Azodicbonamide
AzodicbonaMide Diazene-1,2-dicboxaMide
11AZOBISMETHANAMIDE
Azodicbonamide
Azobisformamide
delta(1,1’)-biurea
Azodicbamide: (Azodicbonamide)
Azoformamide
azobiscbonamide
1,1-AZODICBONAMIDE
AZODICBONAMIDE, MODIFIED (CELLCOM SERIES)
Azodicbamide
genitronac
ficel-a
1,2-Diazenedicboxamide
abfa
AZODICBOXAMIDE
AZODICBONAMIDE FCC
(E)-carbamoyliminourea
Diazenedicboxamide
AZODICBONAMIDE,FCC
genitronc
azodicoxamide
Azo twoforMaMide
Diazene-1,2-dicboxaMide
Carbamoyliminourea
1,1’-azodiformamide
(E)-diazene-1,2-dicboxaMide
1,1'-Azobiscbamid
celogenaz130
DICBAMOYLDIMIDE
AZOFOAM E
MFCD00007958
AzodicbonaMide (ADA) E927
1,1-AZOBISFORMAMIDE
C,C'-azodi(formamide)
EINECS 204-650-8
chkhz21
kempore125
Porofor ADC
Azodiformamide
genitronac2
AZODICBOXYLIC ACID DIAMIDE
celogenaz
genitronac4
AC Blowing agent
1,1’-azobis-formamid
azobiscboxamide
Azodicbonamide1,1'-Azobisformamide
chkhz21r
Density 1.9±0.1 g/cm3
Boiling Point 241.3±23.0 °C at 760 mmHg
Melting Point 220-225 °C (dec.)(lit.)
Molecular Formula C2H4N4O2
Molecular Weight 116.079
Flash Point 99.7±22.6 °C
Exact Mass 116.033424
PSA 110.90000
LogP -0.85
Vapour Pressure 0.0±1.1 mmHg at 25°C
Index of Refraction 1.680
Stability Highly flammable. Incompatible with strong oxidizing agents, strong acids, strong bases, heavy metal salts.
Water Solubility SOLUBLE IN HOT WATER

CHEMICAL IDENTIFICATION

RTECS NUMBER :
LQ1040000
CHEMICAL NAME :
Formamide, 1,1'-azobis-
CAS REGISTRY NUMBER :
123-77-3
LAST UPDATED :
199710
DATA ITEMS CITED :
16
MOLECULAR FORMULA :
C2-H4-N4-O2
MOLECULAR WEIGHT :
116.10
WISWESSER LINE NOTATION :
ZVNUNVZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>6400 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
440 mg/kg
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - respiratory stimulation Gastrointestinal - hypermotility, diarrhea Skin and Appendages - hair
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
42 gm/kg/10D-C
TOXIC EFFECTS :
Endocrine - evidence of thyroid hypofunction Endocrine - changes in thyroid weight
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
233 gm/kg/4W-C
TOXIC EFFECTS :
Endocrine - evidence of thyroid hypofunction
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
207 mg/m3/6H/2W-I
TOXIC EFFECTS :
Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
204 mg/m3/6H/13W-I
TOXIC EFFECTS :
Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
252 mg/kg/1W-I
TOXIC EFFECTS :
Kidney, Ureter, Bladder - hematuria Related to Chronic Data - death
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
217 mg/m3/6H/2W-I
TOXIC EFFECTS :
Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
204 mg/m3/6H/13W-I
TOXIC EFFECTS :
Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
100 ug/plate
REFERENCE :
ENMUDM Environmental Mutagenesis. (New York, NY) V.1-9, 1979-87. For publisher information, see EMMUEG. Volume(issue)/page/year: 8(Suppl 7),1,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81713 No. of Facilities: 1753 (estimated) No. of Industries: 32 No. of Occupations: 60 No. of Employees: 43147 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81713 No. of Facilities: 1210 (estimated) No. of Industries: 18 No. of Occupations: 29 No. of Employees: 42296 (estimated) No. of Female Employees: 17091 (estimated)
Symbol GHS08
GHS08
Signal Word Danger
Hazard Statements H334
Supplemental HS Risk of explosion if heated under confinement.
Precautionary Statements P261-P284-P304 + P340-P342 + P311
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn:Harmful
Risk Phrases R42;R44
Safety Phrases S22-S24-S37
RIDADR UN 3242 4.1/PG 2
WGK Germany 1
RTECS LQ1040000
Packaging Group II
Hazard Class 4.1
HS Code 2924199090
110-21-4 structure

110-21-4

~77%

123-77-3 structure

123-77-3

Literature: Islamgulova; Shitova; Tomilov; Pilyugin; Maslennikov Russian Journal of Applied Chemistry, 1998 , vol. 71, # 7 p. 1176 - 1180
31775-57-2 structure

31775-57-2

~%

123-77-3 structure

123-77-3

Literature: Journal of the American Chemical Society, , vol. 92, p. 2096 - 2100
1972-28-7 structure

1972-28-7

~%

123-77-3 structure

123-77-3

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. <2>52, p. 480
13125-56-9 structure

13125-56-9

~%

50-00-0 structure

50-00-0

471-31-8 structure

471-31-8

123-77-3 structure

123-77-3

Detail
Literature: Chemische Berichte, , vol. 122, p. 745 - 748
6272-66-8 structure

6272-66-8

~%

123-77-3 structure

123-77-3

Literature: Justus Liebigs Annalen der Chemie, , vol. 270, p. 44 Justus Liebigs Annalen der Chemie, , vol. 271, p. 129
HS Code 2927000090
Summary 2927000090 other diazo-, azo- or azoxy-compounds。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%
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