115651-77-9

(1R,2S)-(+)-N,N-Di-n-butylnorephedrin
Chemical Formula
C 17 H 29 NO
CAS Number
115651-77-9
(International)

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Section II.Composition and Information on Ingredients
Toxicology Data
Chemical NameCAS Number Percent (%)TLV/PEL
(1R,2S)-(+)-alpha-[1-(N,N-Di-n-butylamino)ethyl]benzyl115651-77-9Min. 95.0Not available.Not available.
Alcohol(GC,T)

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Section III.Hazards Identification
Acute Health Effects
Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system . Inflam m ation of
the eye is characterized by redness, w atering, and itching. Skin inflam m ation is characterized by itching, scaling,
reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and alw ays w ear proper protective
equipment when handling this compound.
Chronic Health Effects
CARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY : Not available.
There is no know n effect from chronic exposure to this product.Repeated or prolonged exposure to this com pound is
not known to aggravate existing medical conditions.

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Section IV.First Aid Measures
Eye Contact
C heck for and rem ove any contact lenses. D O N O T use an eye ointm ent. Flush eyes w ith running w ater for a m inim um
of 15 m inutes, occasionally lifting the upper and low er eyelids. Seek m edical attention. Treat sym ptom atically and
supportively.
Skin Contact
A fter contact w ith skin, w ash im m ediately w ith plen ty of w ater. G ently and thoroughly w ash the contam inated skin w ith
running w ater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. C over the
irritated skin w ith an em ollient. Seek m edical attention. Treat sym ptom atically and supportively. W ash any
contaminated clothing before reusing.
Inhalation
If the victim is not breathing, perform artificial respiration. Loosen tight clothing such as a collar, tie, belt or w aistband.
If breathing is difficult, oxygen can be administered. Seek medical attention. Treat symptomatically and supportively.
Ingestion
IN D U C E V O M ITIN G by sticking finger in throat. Low er the head so that the vom it w ill not reenter the m outh and throat.
Loosen tight clothing such as a collar, tie, belt, or w aistband. If the victim is not breathing, adm inister artificial
respiration. Exam ine the lips and m outh to ascertain w hether the tissues are dam aged, a possible indication that the
toxic m aterial w as ingested; the absence of such signs, how ever, is not conclusive. Seek im m ediate m edical attention
and, if possible, show the chemical label. Treat symptomatically and supportively.

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Section V.Fire and Explosion Data
Auto-Ignition
FlammabilityNot available.
Combustible.
Flash PointsFlammable Limits
Not available.Not available.
Combustion Products
These products are toxic carbon oxides (CO, CO2), nitrogen oxides (NO, NO2 ).
Fire Hazards
No specific information is available regarding the flammability of this compound in the presence of various materials.
Explosion Hazards
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
No additional information is available regarding the risks of explosion.
Fire Fighting Media
SMALL FIRE: Use DRY chemicals, CO2, water spray or foam.
and Instructions
LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet.
Continued on Next Page
115651-77-9nal)(U.S.).ompany Identificationthyl]benzyl Page 2
Alcohol

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Section VI.Accidental Release Measures
Spill Cleanup
Irritating material.
InstructionsK eep aw ay from heat and sources of ignition. M echanical exhaust required. Stop leak if w ithout risk. Finish cleaning
the spill by rinsing any contam inated surfaces w ith copious am ounts of w ater. C onsult federal, state, and/or local
authorities for assistance on disposal.

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Section VII.Handling and Storage
Handling and Storage
IRRITA N T. K eep aw ay from heat and sources of ignition. M echanical exhaust required. W hen not in use, tightly seal the
container and store in a dry, cool place. A void excessive heat and light. D O N O T ingest. D o not breathe gas, fum es,
Information
vapor or spray. In case of insufficient ventilation, w ear suitable respiratory equipm ent. If ingested, seek m edical advice
im m ediately and show the container or the label. Treat sym ptom atically and supportively. A void contact w ith skin and
eyes.
Always store away from incompatible compounds such as oxidizing agents.

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Section VIII.Exposure Controls/Personal Protection
Engineering Controls
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash station and safety shower is proximal to the work-station location.
Personal Protection
Splash goggles. Lab coat. V apor respirator. Boots. G loves. A M SH A /N IO SH approved respirator m ust be used to avoid
inhalation of the product. Suggested protective clothing m ight not be sufficient; consult a specialist BEFO RE handling
this product.
Exposure Limits
Not available.

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Section IX.Physical and Chemical Properties
Physical state @ 20°CSolubility
Liquid.
Not available.
Specific Gravity0.94 (water=1)
Molecular WeightPartition Coefficient
263.42Not available.
Boiling PointVapor Pressure
143 to 145°C (289.4 to 293°F) @ 2mmHgNot available.
Melting PointVapor Density
Not available.Not available.
Refractive IndexVolatility
Not available.Not available.
Critical TemperatureOdor
Not available.Not available.
ViscosityTaste
Not available.Not available.

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Section X.Stability and Reactivity Data
Stability

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This material is stable if stored under proper conditions. (See Section VII for instructions)
Conditions of Instability
Avoid excessive heat and light.
Incompatibilities
Reactive with oxidizing agents.

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Section XI.Toxicological Information
RTECS Number
Not available.
Routes of Exposure
Eye contact. Inhalation. Ingestion. Skin contact.
Toxicity Data
Not available.
Chronic Toxic EffectsCARCINOGENIC EFFECTS : Not available.
MUTAGENIC EFFECTS : Not available.
TERATOGENIC EFFECTS : Not available.
DEVELOPMENTAL TOXICITY : Not available.
There is no know n effect from chronic exposure to this product.Repeated or prolonged exposure to this com pound is
not known to aggravate existing medical conditions.
Acute Toxic Effects
Irritating to eyes and skin on contact. Inhalation causes irritation of the lungs and respiratory system . Inflam m ation of
the eye is characterized by redness, w atering, and itching. Skin inflam m ation is characterized by itching, scaling,
reddening, or, occasionally, blistering. Follow safe industrial hygiene practices and alw ays w ear proper protective
equipment when handling this compound.
Continued on Next Page
(1R,2S)-(+)-alpha-[1-(N,N-Di-n-butylamino)ethyl]benzyl Page 3
Alcohol

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Section XII.Ecological Information
Ecotoxicity
Not available.
Environmental Fate
Not available.

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Section XIII.Disposal Considerations
Waste Disposal
Recycle to process, if possible. C onsult your local or regional authorities. You m ay be able to dissolve or m ix m aterial
w ith a com bustible solvent and burn in a chem ical incinerator equipped w ith an afterburner and scrubber system .
Observe all federal, state, and local regulations when disposing of this substance.

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Section XIV.Transport Information
DOT Classification
Not a DOT controlled material (United States).
PIN Number
Not applicable.
Proper Shipping Name
Not applicable.
Packing Group (PG)
Not applicable.
DOT Pictograms

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Section XV.Other Regulatory Information and Pictograms
TSCA Chemical InventoryT h is p r o d u c t is NOT o n t h e E P A T o x ic S u b s t a n c e s C o n t r o l A c t (T S C A ) in v e n t o r y . T h e f o llo w in g n o t ic e s a r e r e q u ir e d b y 4 0
(EPA)CFR 720.36 (C) for those products not on the inventory list:
(i) These products are supplied solely for use in research and developm ent by or under the supervision of a technically
qualified individual as defined in 40 CFR 720.0 et sec.
(ii) The health risks of these products have not been fully determ ined. A ny inform ation that is or becom es available w ill
be supplied on an MSDS sheet.
WHMIS Classification
WHMIS CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
(Canada)
EINECS Number (EEC)
Not available.
EEC Risk Statements
R36/37/38- Irritating to eyes, respiratory system and skin.

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SECTION 16 - ADDITIONAL INFORMATION
N/A