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6396-07-2

6396-07-2 structure
6396-07-2 structure

Name diiodo(triphenyl)-λ5-phosphane
Synonyms MFCD00216568
Iodotriphenylphosphoranium iodide
Diiodotriphenylphosphorane
triphenylphosphine diiodide
Triphenylphosphin-diiodid
Diiod-triphenylphosphoran
Dijod-triphenyl-phosphoran
Phosphorane,diiodotriphenyl
Melting Point 210-220ºC(lit.)
Molecular Formula C18H15I2P
Molecular Weight 516.09400
Exact Mass 515.90000
PSA 13.59000
LogP 5.21620
Appearance Powder | Yellow to orange
Storage condition 2-8°C

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TB6100000
CHEMICAL NAME :
Phosphorane, diiodotriphenyl-
CAS REGISTRY NUMBER :
6396-07-2
BEILSTEIN REFERENCE NO. :
2740417
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C18-H15-I2-P
MOLECULAR WEIGHT :
516.10
WISWESSER LINE NOTATION :
IPR&R&R &I &2/10

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
89 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02486
Symbol GHS05 GHS08
GHS05, GHS08
Signal Word Danger
Hazard Statements H314-H317-H334-H361
Precautionary Statements P261-P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C
Risk Phrases 34-42/43-62
Safety Phrases 26-36/37/39-45
RIDADR UN 2923 8/PG 2
WGK Germany 3
RTECS TB6100000

~97%

6396-07-2 structure

6396-07-2

Literature: Grunenthal GMBH Patent: US2009/247505 A1, 2009 ; Location in patent: Page/Page column 15 ; US 20090247505 A1

~86%

6396-07-2 structure

6396-07-2

Literature: Romanenko, V. D.; Tovstenko, V. I.; Markovski, L. N. Synthesis, 1980 , # 10 p. 823 - 825

~%

6396-07-2 structure

6396-07-2

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 49, # 11 p. 2452 - 2458,2165 - 2169

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6396-07-2 structure

6396-07-2

Literature: Justus Liebigs Annalen der Chemie, , vol. 562, p. 187,190, 192

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6396-07-2 structure

6396-07-2

Literature: Justus Liebigs Annalen der Chemie, , vol. 562, p. 187,190, 192

~%

6396-07-2 structure

6396-07-2

Literature: J. Gen. Chem. USSR (Engl. Transl.), , vol. 54, # 6 p. 1245 - 1251,1114 - 1119

~%

6396-07-2 structure

6396-07-2

Literature: Synthesis, , p. 823