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5131-66-8

5131-66-8 structure
5131-66-8 structure

Name Propylene Glycol 1-Monobutyl Ether
Synonyms 1-Butoxy-2-propanol
1-Butoxy-2-hydroxypropane
EINECS 225-878-4
C4H9OCH2CH(CH3)OH
MFCD00021904
1-butoxypropan-2-ol
2-Propanol, 1-butoxy-
Density 0.9±0.1 g/cm3
Boiling Point 171.5±0.0 °C at 760 mmHg
Melting Point <-75ºC
Molecular Formula C7H16O2
Molecular Weight 132.201
Flash Point 54.5±7.7 °C
Exact Mass 132.115036
PSA 29.46000
LogP 1.14
Vapour Pressure 0.4±0.7 mmHg at 25°C
Index of Refraction 1.422

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UA7700000
CHEMICAL NAME :
2-Propanol, 1-butoxy-
CAS REGISTRY NUMBER :
5131-66-8
BEILSTEIN REFERENCE NO. :
1733910
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
C7-H16-O2
MOLECULAR WEIGHT :
132.23
WISWESSER LINE NOTATION :
QY1&1O4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5660 uL/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Gastrointestinal - changes in structure or function of salivary glands Skin and Appendages - hair
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0516797
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NPIRI* Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. (National Assoc. of Printing Ink Research Institute, Francis McDonald Sinclair Memorial Laboratory, Lehigh Univ., Bethlehem, PA 18015) Volume(issue)/page/year: 1,102,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
600 ppm/6H/11D-I
TOXIC EFFECTS :
Liver - changes in liver weight
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0516797 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2187 No. of Facilities: 918 (estimated) No. of Industries: 20 No. of Occupations: 10 No. of Employees: 8427 (estimated) No. of Female Employees: 5583 (estimated)
Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319
Precautionary Statements P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi
Risk Phrases R36/37/38
Safety Phrases 26-36/37/39
RIDADR UN 1987
RTECS UA7700000
Packaging Group III
Hazard Class 3.2
HS Code 2909499000

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Detail
Literature: Dow Global Technologies LLC; TULCHINSKY, Michael, L.; BRIGGS, John, R.; RAND, Cynthia, L. Patent: EP2318346 B1, 2013 ; Location in patent: Paragraph 0072 ;

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5131-66-8

Literature: EASTMAN CHEMICAL COMPANY Patent: US2012/330069 A1, 2012 ; Location in patent: Page/Page column 9-10 ;

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5131-66-8

Literature: Zhang, Yongbo; Lu, Bin; Wang, Xiaoguang; Zhao, Jingxiang; Cai, Qinghai Applied Catalysis A: General, 2011 , vol. 408, # 1-2 p. 125 - 129

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Literature: Takeuchi, Hiroshi; Kitajima, Kunio; Yamamoto, Yasuhiro; Mizuno, Kiyokazu Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1993 , # 2 p. 199 - 203

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Literature: Grobelny, Zbigniew; Stolarzewicz, Andrzej; Maercker, Adalbert; Krompiec, Stanislaw; Bieg, Tadeusz Journal of Organometallic Chemistry, 2002 , vol. 660, # 2 p. 133 - 138

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Literature: Liu, Fei; De Oliveira Vigier, Karine; Pera-Titus, Marc; Pouilloux, Yannick; Clacens, Jean-Marc; Decampo, Floryan; Jerome, Francois Green Chemistry, 2013 , vol. 15, # 4 p. 901 - 909

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Literature: Chlebicki,J. Roczniki Chemii, 1974 , vol. 48, p. 1241 - 1253

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5131-66-8

Detail
Literature: Smith,R.G. et al. Canadian Journal of Chemistry, 1969 , vol. 47, p. 2015 - 2019
HS Code 2909499000
Summary 2909499000. ether-alcohols and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:9.0%. . MFN tariff:5.5%. General tariff:30.0%