4-picoline n-oxide

Modify Date: 2024-01-02 18:00:48

4-picoline n-oxide Structure
4-picoline n-oxide structure
 Common Name 4-picoline n-oxide
CAS Number 1003-67-4 Molecular Weight 109.126
Density 1.0±0.1 g/cm3 Boiling Point 279.2±9.0 °C at 760 mmHg
Molecular Formula C6H7NO Melting Point 182-185 °C(lit.)
MSDS Chinese USA Flash Point 122.6±18.7 °C
Symbol GHS07
GHS07		 Signal Word Warning

 Names

Name 4-Picoline-N-oxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 279.2±9.0 °C at 760 mmHg
Melting Point 182-185 °C(lit.)
Molecular Formula C6H7NO
Molecular Weight 109.126
Flash Point 122.6±18.7 °C
Exact Mass 109.052765
PSA 25.46000
LogP -0.74
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.513
Water Solubility soluble

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UT5800000
CHEMICAL NAME :
Pyridine, 4-methyl-, 1-oxide
CAS REGISTRY NUMBER :
1003-67-4
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C6-H7-N-O
MOLECULAR WEIGHT :
109.14
WISWESSER LINE NOTATION :
T6NJ AO D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1242 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
TOXIA6 Toxicon. (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW, UK) V.1- 1962- Volume(issue)/page/year: 23,815,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - quail
DOSE/DURATION :
750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - wild bird species
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 12,355,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - T1564 No. of Facilities: 76 (estimated) No. of Industries: 2 No. of Occupations: 3 No. of Employees: 636 (estimated)

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36-S24/25
RIDADR NONH for all modes of transport
WGK Germany 1
RTECS UT5800000
HS Code 29333999

 Synthetic Route

4-Picoline structure

4-Picoline

CAS#:108-89-4

~99%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

Literature: Limnios, Dimitris; Kokotos, Christoforos G. Chemistry - A European Journal, 2014 , vol. 20, # 2 p. 559 - 563
4-Picoline structure

4-Picoline

CAS#:108-89-4

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

Isonicotinic acid structure

Isonicotinic acid

CAS#:55-22-1

Pyridine-4-Carboxylic Acid N-Oxide structure

Pyridine-4-Carb...

CAS#:13602-12-5

Literature: WO2006/43075 A1, ; Page/Page column 24-27 ;
4-Picoline structure

4-Picoline

CAS#:108-89-4

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

Isonicotinic acid structure

Isonicotinic acid

CAS#:55-22-1

Literature: WO2006/43075 A1, ; Page/Page column 24-27 ;
3-Mepy structure

3-Mepy

CAS#:108-99-6

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

Pyridine-4-Carboxylic Acid N-Oxide structure

Pyridine-4-Carb...

CAS#:13602-12-5

Literature: Chemistry - A European Journal, , vol. 14, # 8 p. 2340 - 2348
(H2O)5 chromium(III)(4-Me-pyridine-N-oxide) structure

(H2O)5 chromium...

CAS#:933761-80-9

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

N/A structure

N/A

CAS#:14873-01-9

Literature: European Journal of Inorganic Chemistry, , # 14 p. 2894 - 2899
4-Picoline structure

4-Picoline

CAS#:108-89-4

Benzoyl peroxide structure

Benzoyl peroxide

CAS#:94-36-0

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

4-methyl-3-phenylpyridine structure

4-methyl-3-phen...

CAS#:19352-29-5

Detail
Literature: Vidal, S.; Court, J.; Bonnier, J.M. Tetrahedron, 1984 , vol. 40, # 23 p. 4911 - 4920
4-methylpyridine N-oxide hemiperchlorate structure

4-methylpyridin...

CAS#:86931-95-5

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

4-methylpyridine N-oxide perchlorate structure

4-methylpyridin...

CAS#:102862-60-2

Literature: Journal of Solution Chemistry, , vol. 19, # 11 p. 1113 - 1124
4-methyl-1-(((trifluoromethyl)sulfonyl)oxy)pyridin-1-ium trifluoromethanesulfonate structure

4-methyl-1-(((t...

CAS#:93743-73-8

~%

4-picoline n-oxide Structure

4-picoline n-oxide

CAS#:1003-67-4

Literature: Tetrahedron Letters, , vol. 25, # 36 p. 3923 - 3926

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

4-Methylpyridine N-Oxide
4-Methylpyridin-1-oxid
EINECS 213-712-3
PICOLINE-4-N-OXIDE
4-Picoline, 1-oxide (8CI)
4-picoline-oxide
MFCD00006210
4-picoline n-oxide
4-methyl-pyridine N-oxide
γ-Picoline N-oxide
γ-Picoline 1-oxide
gama-Picoline-N-oxide
4-Methylpyridine 1-oxide
Pyridine, 4-methyl-, 1-oxide
4-picoline-1-oxide
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