molybdenum(v) chloride

Modify Date: 2024-01-02 13:25:03

molybdenum(v) chloride Structure
molybdenum(v) chloride structure
Common Name molybdenum(v) chloride
CAS Number 10241-05-1 Molecular Weight 273.22500
Density 2.928 g/mL at 25 °C(lit.) Boiling Point 268 °C(lit.)
Molecular Formula Cl5Mo Melting Point 194 °C(lit.)
MSDS Chinese USA Flash Point N/A
Symbol GHS05 GHS08
GHS05, GHS08
Signal Word Danger

 Names

Name molybdenum pentachloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.928 g/mL at 25 °C(lit.)
Boiling Point 268 °C(lit.)
Melting Point 194 °C(lit.)
Molecular Formula Cl5Mo
Molecular Weight 273.22500
Exact Mass 272.75000
LogP 3.44750
Vapour Pressure 1.75 mm Hg ( 25 °C)
Stability Stable, but moisture and air-sensitive. Contact with water liberates toxic gas. Incompatible with water, strong oxidizing agents.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
QA4690000
CHEMICAL NAME :
Molybdenum pentachloride
CAS REGISTRY NUMBER :
10241-05-1
LAST UPDATED :
199712
DATA ITEMS CITED :
22
MOLECULAR FORMULA :
Cl5-Mo
MOLECULAR WEIGHT :
273.19

 Safety Information

Symbol GHS05 GHS08
GHS05, GHS08
Signal Word Danger
Hazard Statements H314-H351
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C:Corrosive;
Risk Phrases R14;R34
Safety Phrases S26-S36/37/39-S43-S45
RIDADR UN 2508 8/PG 3
WGK Germany 3
RTECS QA4690000
Packaging Group III
Hazard Class 8

 Synthetic Route

~88%

molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Literature: Banares, M. A.; Angoso, A.; Criado, J. J. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1983 , vol. 13, p. 145 - 154

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molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Literature: Chemiker-Zeitung, , vol. 12, p. 5 - 5 Mo: MVol., 56, page 162 - 164

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molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Literature: Gazzetta Chimica Italiana, , vol. 9, p. 539 - 539 Iber. Berz., , p. 288 - 288

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molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Literature: European Journal of Inorganic Chemistry, , # 10 p. 2699 - 2703

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molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Detail
Literature: Journal of Inorganic and Nuclear Chemistry, , vol. 24, p. 309 - 314

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molybdenum(v) chloride Structure

molybdenum(v) c...

CAS#:10241-05-1

Literature: Mezin, A.; Lepage, J.; Paulmier, D. Bulletin de la Societe Chimique de France, 1985 , # 4 p. 660 - 663

 Articles5

More Articles
Synthesis of highly functionalized 9,10-phenanthrenequinones by oxidative coupling using MoCl5.

Org. Lett. 14(12) , 2976-9, (2012)

The strong oxidative power of molybdenum pentachloride gives rise to an efficient oxidative C-C bond formation of benzil derivatives to the corresponding 9,10-phenanthrenequinones. A highly complement...

Genotoxic activities in vivo of cobaltous chloride and other metal chlorides as assayed in the Drosophila wing spot test.

Mutat. Res. 320(1-2) , 133-40, (1994)

A series of metal chlorides were subjected to the wing spot test of Drosophila melanogaster. In the test, larvae trans-heterozygous for the wing-hair mutations mwh and flr were orally treated at the t...

Novel domino oxidative coupling: C-C bond formation sequence to highly functionalized dibenzo[a,c]cycloheptenes.

Org. Lett. 13(5) , 916-9, (2011)

A domino sequence involving various MoCl(5)-mediated oxidations followed by trapping and supposed [3,3]-sigmatropic rearrangement provides a fast access to the full carbon skeleton of metasequirin-B. ...

 Synonyms

EINECS 233-575-3
MFCD00003467
Molybdenum(V) chloride
pentachloromolybdenum