3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one

Modify Date: 2024-01-18 22:52:43

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure
3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one structure
Common Name 3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one
CAS Number 109299-92-5 Molecular Weight 155.15100
Density 1.239 g/cm3 Boiling Point 216.2ºC at 760 mmHg
Molecular Formula C7H9NO3 Melting Point 37-41ºC
MSDS N/A Flash Point 84.5ºC

 Names

Name 3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.239 g/cm3
Boiling Point 216.2ºC at 760 mmHg
Melting Point 37-41ºC
Molecular Formula C7H9NO3
Molecular Weight 155.15100
Flash Point 84.5ºC
Exact Mass 155.05800
PSA 46.61000
LogP 0.47920
Vapour Pressure 0.142mmHg at 25°C
Index of Refraction 1.513

 MSDS

Name: 3-[(E)-2-Butenoyl]-1 3-oxazolidin-2-one 99% Material Safety Data Sheet
Synonym:
CAS: 109299-92-5
Section 1 - Chemical Product MSDS Name:3-[(E)-2-Butenoyl]-1 3-oxazolidin-2-one 99% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
109299-92-5 3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-on 99% unlisted
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Keep refrigerated. (Store below 4C/39F.) Store under nitrogen.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 109299-92-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline powder
Color: off-white - light yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 37.00 - 41.00
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H9NO3
Molecular Weight: 155.0679

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Not available.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 109299-92-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 109299-92-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 109299-92-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109299-92-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases 24/25
HS Code 2934999090

 Synthetic Route

~97%

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure

3-[(E)-2-Buteno...

CAS#:109299-92-5

Literature: Bull, Steven D.; Davies, Stephen G.; Garner, A. Christopher; Kruchinin, Dennis; Key, Min-Suk; Roberts, Paul M.; Savory, Edward D.; Smith, Andrew D.; Thomson, James E. Organic and Biomolecular Chemistry, 2006 , vol. 4, # 15 p. 2945 - 2964

~92%

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure

3-[(E)-2-Buteno...

CAS#:109299-92-5

Literature: Velthuisen, Emile J.; Danishefsky, Samuel J. Journal of the American Chemical Society, 2007 , vol. 129, # 35 p. 10640 - 10641

~66%

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure

3-[(E)-2-Buteno...

CAS#:109299-92-5

Literature: Soloshonok, Vadim A.; Cai, Chaozhong; Hruby, Victor J.; Van Meervelt, Luc; Yamazaki, Takashi Journal of Organic Chemistry, 2000 , vol. 65, # 20 p. 6688 - 6696

~79%

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure

3-[(E)-2-Buteno...

CAS#:109299-92-5

Literature: Matsuo, Jun-Ichi; Aizawa, Yayoi Tetrahedron Letters, 2005 , vol. 46, # 3 p. 407 - 410

~49%

3-[(E)-2-Butenoyl]-1,3-oxazolidin-2-one Structure

3-[(E)-2-Buteno...

CAS#:109299-92-5

Literature: Knol, Joop; Feringa, Ben L. Synthetic Communications, 1996 , vol. 26, # 2 p. 261 - 268

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

3-crotonoyl-1,3-oxazolidin-2-one
crotonyl oxazolidinone
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