Butyltrichlorotin

Modify Date: 2024-01-02 17:46:05

Butyltrichlorotin Structure
Butyltrichlorotin structure
Common Name Butyltrichlorotin
CAS Number 1118-46-3 Molecular Weight 282.183
Density 1.693 g/mL at 25 °C(lit.) Boiling Point 226.8±9.0 °C at 760 mmHg
Molecular Formula C4H9Cl3Sn Melting Point -63°C
MSDS Chinese USA Flash Point 91.0±18.7 °C
Symbol GHS05 GHS07 GHS09
GHS05, GHS07, GHS09
Signal Word Danger

 Names

Name Butyltin trichloride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.693 g/mL at 25 °C(lit.)
Boiling Point 226.8±9.0 °C at 760 mmHg
Melting Point -63°C
Molecular Formula C4H9Cl3Sn
Molecular Weight 282.183
Flash Point 91.0±18.7 °C
Exact Mass 281.879181
LogP 0.50
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction n20/D 1.523(lit.)
Water Solubility SOLUBLE

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
WH6780000
CHEMICAL NAME :
Stannane, butyltrichloro-
CAS REGISTRY NUMBER :
1118-46-3
BEILSTEIN REFERENCE NO. :
3535350
LAST UPDATED :
199712
DATA ITEMS CITED :
33
MOLECULAR FORMULA :
C4-H9-Cl3-Sn
MOLECULAR WEIGHT :
282.17
WISWESSER LINE NOTATION :
G-SN-G&G&4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2140 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3 gm/kg
SEX/DURATION :
female 7-8 day(s) after conception
TOXIC EFFECTS :
Reproductive - Maternal Effects - other effects Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)

MUTATION DATA

TYPE OF TEST :
Mutation test systems - not otherwise specified
TEST SYSTEM :
Bacteria - Escherichia coli
REFERENCE :
MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 280,195,1992 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ORGANOTIN COMPOUND-air:10H TWA 0.1 mg(Sn)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5779 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1822 (estimated) No. of Female Employees: 272 (estimated)

 Safety Information

Symbol GHS05 GHS07 GHS09
GHS05, GHS07, GHS09
Signal Word Danger
Hazard Statements H314-H332-H335-H410
Precautionary Statements P261-P273-P280-P305 + P351 + P338-P310-P501
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes C:Corrosive
Risk Phrases R20/21;R34
Safety Phrases S26-S27-S28-S36/37/39-S45
RIDADR UN 3265 8/PG 2
WGK Germany 1
RTECS WH6780000
Packaging Group II
Hazard Class 6.1
HS Code 2931900090

 Synthetic Route

~56%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Chugoku Marine Paints, Ltd. Patent: US4046791 A1, 1977 ;

~0%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Lo Fiego, Marcos J.; Badajoz, Mercedes A.; Domini, Claudia; Chopa, Alicia B.; Lockhart, Maria T. Ultrasonics Sonochemistry, 2013 , vol. 20, # 3 p. 826 - 832

~96%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108 Full Text Show Details Carlisle Chemical Works, Inc. Patent: NL6513659 , 1966 ; C.A., 1966 , vol. 65, p. 7218

~%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Detail
Literature: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108 US3297732 , ; C.A., , vol. 66, p. 115807

~%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Journal of Applied Chemistry, , vol. 7, p. 356,362

~%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108 Functionally Substituted Organotin Compounds, Tin Research Institute, Greenford 1958, S. 1/128

~%

Butyltrichlorotin Structure

Butyltrichlorotin

CAS#:1118-46-3

Literature: Sn: Org.Verb.1, 1.1.1.5.4.5, page 106 - 108 DE1222503 , ; C.A., , vol. 65, p. 13763

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

Butyltrichlorostannane
Monobutyltin Trichloride(Mbtcl)
Butyltrichlorotin
Stannane, trichlorobutyl-
trichlorobutyltin
MFCD00000515
Stannane, butyltrichloro-
Trichlorobutylstannane
EINECS 214-263-6
Butyl(trichloro)stannane
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