Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Modify Date: 2024-01-08 18:47:59

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure
Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate structure
Common Name Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
CAS Number 112741-49-8 Molecular Weight 353.412
Density 1.2±0.1 g/cm3 Boiling Point 509.6±50.0 °C at 760 mmHg
Molecular Formula C21H23NO4 Melting Point 206ºC (dec.)
MSDS Chinese USA Flash Point 262.0±30.1 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name (2R,3S)-tert-Butyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 509.6±50.0 °C at 760 mmHg
Melting Point 206ºC (dec.)
Molecular Formula C21H23NO4
Molecular Weight 353.412
Flash Point 262.0±30.1 °C
Exact Mass 353.162720
PSA 55.84000
LogP 3.45
Vapour Pressure 0.0±1.3 mmHg at 25°C
Index of Refraction 1.562
Storage condition 2~8℃

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport

 Synthetic Route

~73%

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure

Tert-butyl-(2R,...

CAS#:112741-49-8

Literature: Williams, Robert M.; Sinclair, Peter J.; Zhai, Dongguan; Chen, Daimo Journal of the American Chemical Society, 1988 , vol. 110, # 5 p. 1547 - 1557

~%

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure

Tert-butyl-(2R,...

CAS#:112741-49-8

Literature: Synlett, , # 4 art. no. Y04304ST, p. 693 - 696

~82%

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure

Tert-butyl-(2R,...

CAS#:112741-49-8

Literature: Yeo, David J.; Warriner, Stuart L.; Wilson, Andrew J. Chemical Communications, 2013 , vol. 49, # 80 p. 9131 - 9133

~%

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure

Tert-butyl-(2R,...

CAS#:112741-49-8

Literature: Synlett, , # 4 art. no. Y04304ST, p. 693 - 696

~%

Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate Structure

Tert-butyl-(2R,...

CAS#:112741-49-8

Literature: Journal of the American Chemical Society, , vol. 110, # 5 p. 1547 - 1557

 Synonyms

tert-Butyl (2R,3S)-(−)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
2-Methyl-2-propanyl (2R,3S)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2R,3S)-
(2R,3S)-(−)-N-Boc-6-oxo-2,3-diphenylmorpholine
N-Boc(2R, 3S)-(-)-6-oxo-2,3-diphenyl-4-morpholine carboxylate
Tert-butyl-(2R,3S)-(-)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
4-Morpholinecarboxylic acid, 6-oxo-2,3-diphenyl-, 1,1-dimethylethyl ester, (2S,3S)-
tert-Butyl-(2R,3S)-6-oxo-2,3-diphenylmorpholin-4-carboxylat
tert-Butyl (2R,3S)-6-oxo-2,3-diphenylmorpholine-4-carboxylate
2-Methyl-2-propanyl (2S,3S)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
MFCD00074955
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