4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine structure
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Common Name | 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine | ||
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CAS Number | 115091-29-7 | Molecular Weight | 401.58700 | |
Density | 1.004g/cm3 | Boiling Point | 535.7ºC at 760 mmHg | |
Molecular Formula | C27H35N3 | Melting Point | 215-217ºC(lit.) | |
MSDS | Chinese USA | Flash Point | 220.4ºC | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | 4-tert-butyl-2,6-bis(4-tert-butylpyridin-2-yl)pyridine |
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Synonym | More Synonyms |
Density | 1.004g/cm3 |
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Boiling Point | 535.7ºC at 760 mmHg |
Melting Point | 215-217ºC(lit.) |
Molecular Formula | C27H35N3 |
Molecular Weight | 401.58700 |
Flash Point | 220.4ºC |
Exact Mass | 401.28300 |
PSA | 38.67000 |
LogP | 7.09810 |
Vapour Pressure | 5.19E-11mmHg at 25°C |
Index of Refraction | 1.537 |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Hazard Codes | Xi: Irritant; |
Risk Phrases | R36/37/38 |
Safety Phrases | S26 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2933399090 |
HS Code | 2933399090 |
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Summary | 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species.
J. Am. Chem. Soc. 135(22) , 8141-4, (2013) Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, the... |
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Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalyst.
J. Am. Chem. Soc. 128(40) , 13175-83, (2006) The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling react... |
MFCD02093731 |
4,4',4''-Tri-tert-butyl-2,2':6',2''-terpyridine |