4-O-BENZYL-L-RHAMNAL

Modify Date: 2025-08-25 19:46:18

4-O-BENZYL-L-RHAMNAL Structure
4-O-BENZYL-L-RHAMNAL structure
 Common Name 4-O-BENZYL-L-RHAMNAL
CAS Number 117249-16-8 Molecular Weight 220.26400
Density 1.15 g/cm3 Boiling Point 352.6ºC at 760 mmHg
Molecular Formula C13H16O3 Melting Point 111-113ºC(lit.)
MSDS N/A Flash Point 167.1ºC

 Names

Name (2S,3R,4S)-2-methyl-3-phenylmethoxy-3,4-dihydro-2H-pyran-4-ol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.15 g/cm3
Boiling Point 352.6ºC at 760 mmHg
Melting Point 111-113ºC(lit.)
Molecular Formula C13H16O3
Molecular Weight 220.26400
Flash Point 167.1ºC
Exact Mass 220.11000
PSA 38.69000
LogP 1.86510
Vapour Pressure 1.4E-05mmHg at 25°C
Index of Refraction 1.56
InChIKey ZPIBWTYMFFSTBY-DRZSPHRISA-N
SMILES CC1OC=CC(O)C1OCc1ccccc1

 Safety Information

Safety Phrases 24/25

 Synthetic Route

Benzyl bromide structure

Benzyl bromide

CAS#:100-39-0

3,4-Di-O-acetyl-L-rhamnal structure

3,4-Di-O-acetyl...

CAS#:34819-86-8

~32%

4-O-BENZYL-L-RHAMNAL Structure

4-O-BENZYL-L-RHAMNAL

CAS#:117249-16-8

(2S,3S,4S)-4-(benzyloxy)-2-methyl-3,4-dihydro-2H-pyran-3-ol structure

(2S,3S,4S)-4-(b...

CAS#:106988-69-6

Literature: Dow AgroSciences LLC; Meyer, Kevin G.; Bravo-Altamirano, Karla; Renga, James M.; Herrick, Jessica; Nugent, Benjamin M.; Boebel, Timothy A.; Li, Fangzheng; Wang, Nick X.; Owen, W. John; Graupner, Paul R.; Yao, Chenglin; Heemstra, Ronald J. Patent: US2013/296375 A1, 2013 ; Location in patent: Paragraph 0196; 0197 ;
Benzyl bromide structure

Benzyl bromide

CAS#:100-39-0

2-methyl-3,4-dihydro-2H-pyran-3,4-diol structure

2-methyl-3,4-di...

CAS#:53657-42-4

~31%

4-O-BENZYL-L-RHAMNAL Structure

4-O-BENZYL-L-RHAMNAL

CAS#:117249-16-8

(2S,3S,4S)-4-(benzyloxy)-2-methyl-3,4-dihydro-2H-pyran-3-ol structure

(2S,3S,4S)-4-(b...

CAS#:106988-69-6

Detail
Literature: Thiem, Joachim; Klaffke, Werner; Springer, Dirk Carbohydrate Research, 1988 , vol. 174, p. 201 - 210
(-)-(2S,3S)-3-(Benzyloxy)-2-methyl-2,3-dihydro-4H-pyran-4-one structure

(-)-(2S,3S)-3-(...

CAS#:149561-65-9

~%

1,5-Anhydro-4-O-benzyl-2,6-dideoxy-L-ribo-hex-1-enitol structure

1,5-Anhydro-4-O...

CAS#:106988-70-9

4-O-BENZYL-L-RHAMNAL Structure

4-O-BENZYL-L-RHAMNAL

CAS#:117249-16-8

Literature: Kirschning, Andreas; Hary, Ulrike; Plumeier, Claus; Ries, Monika; Rose, Lars Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 4 p. 519 - 528
(2S,3S,4S)-2-methyl-3,4-bis(phenylmethoxy)-3,4-dihydro-2H-pyran structure

(2S,3S,4S)-2-me...

CAS#:117249-17-9

~%

4-O-BENZYL-L-RHAMNAL Structure

4-O-BENZYL-L-RHAMNAL

CAS#:117249-16-8

Literature: Kirschning, Andreas; Hary, Ulrike; Plumeier, Claus; Ries, Monika; Rose, Lars Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 4 p. 519 - 528

 Synonyms

4-O-Benzyl-L-rhamnal
4-O-Benzyl-6-deoxy-L-glucal
1,5-Anhydro-4-O-benzyl-2,6-dideoxy-L-arabino-hex-1-enitol
(4S,6S,5R)-6-methyl-5-(phenylmethoxy)-4H-5,6-dihydropyran-4-ol
(2S,3R,4S)-3-(benzyloxy)-2-methyl-3,4-dihydro-2H-pyran-4-ol
1,5-Anhydro-4-O-benzyl-2,6-didesoxy-L-arabino-hex-1-enitol
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