(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE

Modify Date: 2024-01-10 10:35:12

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure
(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE structure
Common Name (S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE
CAS Number 118535-62-9 Molecular Weight 186.29400
Density N/A Boiling Point 249.6ºC at 760mmHg
Molecular Formula C10H22N2O Melting Point N/A
MSDS N/A Flash Point 104.8ºC

 Names

Name (2S)-2-(3-methoxypentan-3-yl)pyrrolidin-1-amine

 Chemical & Physical Properties

Boiling Point 249.6ºC at 760mmHg
Molecular Formula C10H22N2O
Molecular Weight 186.29400
Flash Point 104.8ºC
Exact Mass 186.17300
PSA 38.49000
LogP 2.16790
Vapour Pressure 0.0227mmHg at 25°C
Index of Refraction 1.475-1.477

 MSDS

Name: (s)-(-)-Amino-2-(1 -methoxy-1 -ethylpropyl )pyrrolidine Material Safety Data Sheet
Synonym: SAE
CAS: 118535-62-9
Section 1 - Chemical Product MSDS Name:(s)-(-)-Amino-2-(1 -methoxy-1 -ethylpropyl )pyrrolidine Material Safety Data Sheet
Synonym:SAE

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
118535-62-9 (S)-(-)-Amino-2-(1'-methoxy-1'-ethylpr 100 unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.The toxicological properties of this material have not been fully investigated.Moisture sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Avoid ingestion and inhalation. Do not allow contact with water. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Deep freeze (below -20C). Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 118535-62-9: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 67 - 70 deg C @ .10mm Hg
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 118535-62-9 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(S)-(-)-Amino-2-(1'-methoxy-1'-ethylpropyl)pyrrolidine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 118535-62-9: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 118535-62-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 118535-62-9 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S37/39
HS Code 2933990090

 Synthetic Route

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

~%

(S)-1-AMINO-2-(DIETHYLMETHOXYMETHYL)PYRROLIDINE Structure

(S)-1-AMINO-2-(...

CAS#:118535-62-9

Literature: Enders, Dieter; Kipphardt, Helmut; Gerdes, Peter; Brena-Valle, Leonardo J.; Bhushan, Vidya Bulletin des Societes Chimiques Belges, 1988 , vol. 97, # 8-9 p. 691 - 704

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%