1,2,5,6-cyclooctanetetraylidene, nickel salt structure
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Common Name | 1,2,5,6-cyclooctanetetraylidene, nickel salt | ||
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CAS Number | 1295-35-8 | Molecular Weight | 266.992 | |
Density | N/A | Boiling Point | 153.5ºC at 760 mmHg | |
Molecular Formula | C16H24Ni | Melting Point | 60 °C (dec.)(lit.) | |
MSDS | Chinese USA | Flash Point | 31.7ºC | |
Symbol |
GHS02, GHS08 |
Signal Word | Danger |
Name | Bis(1,5-cyclooctadiene)nickel(0) |
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Synonym | More Synonyms |
Boiling Point | 153.5ºC at 760 mmHg |
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Melting Point | 60 °C (dec.)(lit.) |
Molecular Formula | C16H24Ni |
Molecular Weight | 266.992 |
Flash Point | 31.7ºC |
Exact Mass | 266.060547 |
LogP | 5.34560 |
Vapour Pressure | 4.25mmHg at 25°C |
Storage condition | 0-6°C |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATAMUTATION DATA
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Symbol |
GHS02, GHS08 |
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Signal Word | Danger |
Hazard Statements | H228-H334-H351 |
Precautionary Statements | P210-P261-P281-P342 + P311 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | F:Flammable;T:Toxic; |
Risk Phrases | R45;R11 |
Safety Phrases | S36/37 |
RIDADR | UN 1325 4.1/PG 2 |
WGK Germany | 3 |
RTECS | QR6135000 |
Packaging Group | I |
Hazard Class | 4.2 |
~81% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Tenorio, Manuel Jimenez; Puerta, M. Carmen; Salcedo, Isabel; Valegra, Pedro Journal of the Chemical Society, Dalton Transactions, 2001 , p. 653 - 657 |
~60% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Schroeder, Wolfgang; Poerschke, Klaus R. Journal of Organometallic Chemistry, 1987 , vol. 322, p. 385 - 392 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Angewandte Chemie, , vol. 85, p. 620 - 621 Diss. Bochum 1973 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Chemische Berichte, , vol. 123, p. 1267 - 1274 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Angewandte Chemie, , vol. 99, p. 953 - 954 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Organometallics, , vol. 29, # 11 p. 2386 - 2389 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Kaschube, Wilfried; Poerschke, Klaus R.; Bonrath, Werner; Krueger, Carl; Wilke, Guenther Angewandte Chemie, 1989 , vol. 101, p. 790 - 792 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Organometallics, , vol. 1, p. 401 - 402 |
~% 1,2,5,6-cyclooc... CAS#:1295-35-8 |
Literature: Journal of the Chemical Society, Chemical Communications, , p. 1098 - 1099 Ni: Org.Verb.2, 1.4.2.1.1, page 87 - 88 |
Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.
Dalton Trans. 43(42) , 15997-6005, (2014) Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while main... |
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Nickel-catalyzed thioallylation of alkynes with allyl phenyl sulfides.
Org. Lett. 9 , 263, (2007) Allylic sulfides add to alkynes in the presence of nickel complexes efficiently to afford thio-1,4-dienes regio- and stereoselectively. Functional groups such as alkoxy, siloxy, hydroxy, carboalkoxy, ... |
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A boron-doped helicene as a highly soluble, benchtop-stable green emitter.
Chem. Commun. (Camb.) 51(87) , 15808-10, (2015) The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility ... |
EINECS 215-072-0 |
Bis(cyclooctadiene)nickel Ni(COD)2 |
1,2,5,6-Cyclooctanetetraylidene - nickel (2:1) |
1,2,5,6-cyclooctanetetraylidene, nickel salt |
(1Z,5Z)-cycloocta-1,5-diene,nickel |
cyclooctane-1,2,5,6-tetraylidene - nickel (2:1) |
1,2,5,6-Cyclooctanetetraylidene, nickel salt (2:1) |
MFCD00058902 |