Tetraammineplatinum tetrachloroplatinate

Modify Date: 2024-01-10 18:04:17

Tetraammineplatinum tetrachloroplatinate Structure
Tetraammineplatinum tetrachloroplatinate structure
Common Name Tetraammineplatinum tetrachloroplatinate
CAS Number 13820-46-7 Molecular Weight 600.09000
Density N/A Boiling Point N/A
Molecular Formula Cl4H12N4Pt2 Melting Point 320ºC (dec.)(lit.)
MSDS N/A Flash Point N/A

 Names

Name tetraammineplatinum(ii) tetrachloro
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 320ºC (dec.)(lit.)
Molecular Formula Cl4H12N4Pt2
Molecular Weight 600.09000
Exact Mass 597.91100
PSA 12.96000
LogP 4.04860

 MSDS


Section 1: Product Identification
Chemical Name:Tetraammineplatinum (II) tetrachloroplatinate (II), 99%
CAS Registry Number:13820-46-7
Formula:[Pt(NH3)4][PtCl4]
EINECS Number:237-501-0
Chemical Family:metal-ammine complexes
Synonym:Platinum (II) tetraammine tetrachloroplatinate (II)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13820-46-7100%1mg/m3(as-Pt)no data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May cause sensitization by skin contact.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin. May cause sensitization by skin contact.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
Acute Health Affects:
and running of the nose. Skin exposure may lead to dermatitis.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:green pwdr.
Molecular Weight:600.12
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:active metals
Decomposition Products:ammonium chloride, nitrogen oxides, and platinum salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Not regulated by Title 313.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes T: Toxic;
Risk Phrases R25
Safety Phrases 22-26-36/37/39-45
RIDADR UN 3288 6.1/PG 3

 Synthetic Route

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Tetraammineplatinum tetrachloroplatinate Structure

Tetraammineplat...

CAS#:13820-46-7

Literature: C. r. URSS, , vol. 54, p. 697 - 699 Doklady, , vol. 54, p. 701 - 704

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Tetraammineplatinum tetrachloroplatinate Structure

Tetraammineplat...

CAS#:13820-46-7

Literature: American Chemical Journal, , vol. 3, p. 350 - 351

 Synonyms

tetraammineplatinum tetrachloroplatinate
MFCD01459899
{Pta4}{PtCl4} [Pt(NH3)4][PtCl4],green
Tetraammineplatinous tetrachloroplatinate
tetraammine-platinum(2++(sp-4-1)-platinum(2++(sp-4-1)-tetrachloroplatinate(2-)(1:1)
EINECS 237-501-0
Tetrammin-platin(II)-tetrachloro-platinat(II)
tetraammine-platinum(II) tetrachloro-platinate(II)
Platinum(2+),tetraammine-,(sp-4-1)-,(sp-4-1)-tetrachloroplatinate(2-) (1:1)
Magnus green salt
Tetrammineplatinum(ii) tetrachloroplatinate(ii)
{Pta4}{PtCl4}
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