(Acetylacetonato)dicarbonyliridium (I)

Modify Date: 2024-01-12 01:14:35

(Acetylacetonato)dicarbonyliridium (I) Structure
(Acetylacetonato)dicarbonyliridium (I) structure
Common Name (Acetylacetonato)dicarbonyliridium (I)
CAS Number 14023-80-4 Molecular Weight 347.34500
Density N/A Boiling Point 100ºC (0.05 torr)
Molecular Formula C7H7IrO4 Melting Point >145℃
MSDS N/A Flash Point N/A

 Use of (Acetylacetonato)dicarbonyliridium (I)


(Acetylacetonato)dicarbonyliridium(I) is a catalyst for isomerization and anti-Markovnikov arylation of olefins. It is also a reactant for oxidative addition of perfluoroalkyl iodides, synthesis of iridium heterocycles, scaffolding of iridium complexes, metal carbonyl cluster synthesis, and mixed-bridged bimetallic d8 complex synthesis.

 Names

Name (acetylacetonato)dicarbonyliridium(i)
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 100ºC (0.05 torr)
Melting Point >145℃
Molecular Formula C7H7IrO4
Molecular Weight 347.34500
Exact Mass 347.99700
PSA 26.30000
LogP 0.54410
Stability store cold

 MSDS


Section 1: Product Identification
Chemical Name:Dicarbonylacetylacetonato iridium (I), 98%
CAS Registry Number:14023-80-4
Formula:Ir(CO)2(CH3COCHCOCH3)
EINECS Number:none
Chemical Family:metal carbonyl complexes
Synonym:Dicarbonyl(2.4-pentanedionato)iridium (I)

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14023-80-4100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Inhalation, skin contact
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store cold in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothes and gloves. Consult glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:copper brown xtl.
Molecular Weight:347.35
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable (store cold)
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and iridium compounds.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases 22-26-36
RIDADR UN3466
WGK Germany 3
Packaging Group III
Hazard Class 6.1

 Synonyms

Dicarbonyl(2,4-pentanedionato)iridium
2,4-Pentanedionatodicarbonyl iridium
MFCD00049135
IRIDIUM I DICARBONYL PENTANEDIONATE
Dicarbonyl(2,4-pentanedionato)iridium(I)
(Acetylacetonato)dicarbonyliridium(I)