Diadamantan-1-ylphosphinous chloride

Modify Date: 2024-01-09 18:01:10

Diadamantan-1-ylphosphinous chloride Structure
Diadamantan-1-ylphosphinous chloride structure
Common Name Diadamantan-1-ylphosphinous chloride
CAS Number 157282-19-4 Molecular Weight 336.879
Density N/A Boiling Point 413.3±12.0 °C at 760 mmHg
Molecular Formula C20H30ClP Melting Point 168-173°C (lit.)
MSDS Chinese USA Flash Point 203.8±19.6 °C
Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger

 Names

Name Di(adamantan-1-yl)chlorophosphine
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 413.3±12.0 °C at 760 mmHg
Melting Point 168-173°C (lit.)
Molecular Formula C20H30ClP
Molecular Weight 336.879
Flash Point 203.8±19.6 °C
Exact Mass 336.177368
PSA 13.59000
LogP 7.59
Vapour Pressure 0.0±0.9 mmHg at 25°C

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger
Hazard Statements H261-H314-H317-H351-H372-H420
Supplemental HS Reacts violently with water.
Precautionary Statements P231 + P232-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P370 + P378
Hazard Codes F+
Risk Phrases 14-23/24/25-34-40-48/23-59
Safety Phrases 26-36/37/39-45-59
RIDADR UN 3096 4.3(8) / PGII

 Synthetic Route

~98%

Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Koellhofer, Axel; Plenio, Herbert Chemistry - A European Journal, 2003 , vol. 9, # 6 p. 1416 - 1425

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Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: US6307087 B1, ;

~91%

Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Beller, Matthias; Ehrentraut, Andreas; Ehrentraut, Wilhelm Hubert; Ehrentraut, Theresia Elisabeth; Fuhrmann, Christa; Zapf, Alexander Patent: US2004/68131 A1, 2004 ;

~68%

Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Lavrova, E. A.; Koidan, G. N.; Marchenko, A. P.; Pinchuk, A. M. Russian Journal of General Chemistry, 1994 , vol. 64, # 9.2 p. 1393 - 1394 Zhurnal Obshchei Khimii, 1994 , vol. 64, # 9 p. 1556 - 1557

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Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 102, # 1-4 p. 211 - 216

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Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 102, # 1-4 p. 211 - 216

~28%

Diadamantan-1-ylphosphinous chloride Structure

Diadamantan-1-y...

CAS#:157282-19-4

Literature: Goerlich, Jens R.; Fischer, Axel; Jones, Peter G.; Schmutzler, Reinhard Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994 , vol. 49, # 6 p. 801 - 811

 Synonyms

Phosphinous chloride, P,P-ditricyclo[3.3.1.1]dec-1-yl-
Di(1-adamantyl)chlorophosphine
Diadamantan-1-ylphosphinous chloride