Chloro(diisobutyl)aluminum

Modify Date: 2024-01-05 12:08:31

Chloro(diisobutyl)aluminum Structure
Chloro(diisobutyl)aluminum structure
 Common Name Chloro(diisobutyl)aluminum
CAS Number 1779-25-5 Molecular Weight 176.663
Density 0.723 Boiling Point 152°C 10mm
Molecular Formula C8H18AlCl Melting Point -40°C
MSDS N/A Flash Point -18°C

 Names

Name chloro-bis(2-methylpropyl)alumane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.723
Boiling Point 152°C 10mm
Melting Point -40°C
Molecular Formula C8H18AlCl
Molecular Weight 176.663
Flash Point -18°C
Exact Mass 176.091248
LogP 3.90950
Index of Refraction n20/D 1.4506(lit.)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD0560000
CHEMICAL NAME :
Aluminum, chlorodiisobutyl-
CAS REGISTRY NUMBER :
1779-25-5
LAST UPDATED :
199712
DATA ITEMS CITED :
15
MOLECULAR FORMULA :
C8-H18-Al-Cl
MOLECULAR WEIGHT :
176.69
WISWESSER LINE NOTATION :
1Y1&1-AL-G1Y1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
67 ppm/1H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1216,1986
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
680 gm/kg/15M
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - acute pulmonary edema Lungs, Thorax, or Respiration - dyspnea Liver - other changes
REFERENCE :
MELAAD Medicina del Lavoro. Industrial Medicine. (Via S. Barnaba, 8, 20122 Milan, Italy) V.16- 1925- Volume(issue)/page/year: 58,290,1967 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

 Safety Information

Hazard Codes N-C-F,T+,F
Risk Phrases 67-65-50/53-35-14/15-11-34-26-17
Safety Phrases 6A-57-45-43E-36/37/39-29-26-16
RIDADR 3052
RTECS BD0560000
Packaging Group I
Hazard Class 4.3
HS Code 2903199000

 Synthetic Route

rac-[bis(2-trimethylsilyl-4-tert-butyl-η(5)-cyclopentadienyl)dimethylsilane]dichlorozirconium structure

rac-[bis(2-trim...

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Diisobutylaluminium hydride structure

Diisobutylalumi...

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~%

meso-Me2Si(2-Me3Si-4-Me3C-C5H2)2ZrH(μ-H)2Al(i-Bu)2 structure

meso-Me2Si(2-Me...

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Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 130, # 51 p. 17423 - 17433
Dimethylsilylbis(cyclopentadienyl)zirconium dichloride structure

Dimethylsilylbi...

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Diisobutylaluminium hydride structure

Diisobutylalumi...

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~%

Me2Si(C5H4)2ZrCl(μ-H)2Al(i-Bu)2 structure

Me2Si(C5H4)2ZrC...

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Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 130, # 51 p. 17423 - 17433
(Me2Si)2(2,4-i-Pr2-C5H)(C5H3)ZrCl2 structure

(Me2Si)2(2,4-i-...

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Diisobutylaluminium hydride structure

Diisobutylalumi...

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~%

(Me2Si)2(2,4-i-Pr2-C5H)(C5H3)ZrCl(μ-H)2Al(i-Bu)2 structure

(Me2Si)2(2,4-i-...

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Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 130, # 51 p. 17423 - 17433
1,1'-Isopropylidenezirconocene Dichloride structure

1,1'-Isopropyli...

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Diisobutylaluminium hydride structure

Diisobutylalumi...

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~%

Me2C(C5H4)2ZrCl(μ-H)2Al(i-Bu)2 structure

Me2C(C5H4)2ZrCl...

CAS#:1094077-56-1

Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 130, # 51 p. 17423 - 17433
[isopropylidene(bisindenyl)]ZrCl2 structure

[isopropylidene...

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Diisobutylaluminium hydride structure

Diisobutylalumi...

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~%

meso-Me2C(indenyl)2ZrCl(μ-H)2Al(i-Bu)2 structure

meso-Me2C(inden...

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Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 130, # 51 p. 17423 - 17433
Triisobutylaluminum structure

Triisobutylaluminum

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dichloroisobutylaluminium structure

dichloroisobuty...

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~%

Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Journal of the American Chemical Society, , vol. 120, # 20 p. 5124 - 5125
Triisobutylaluminum structure

Triisobutylaluminum

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~%

Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Justus Liebigs Annalen der Chemie, , vol. 608, p. 1,6 Journal of Polymer Science, , vol. 38, p. 51,57
Hydrochloric acid structure

Hydrochloric acid

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Tetra-(isobutyl)-dialuminium structure

Tetra-(isobutyl...

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~%

Isobutane Residual Solvent Standard structure

Isobutane Resid...

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dichloroisobutylaluminium structure

dichloroisobuty...

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Detail
Literature: Organometallics, , vol. 4, p. 1362 - 1364
Aluminium chloride structure

Aluminium chloride

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Triisobutylaluminum structure

Triisobutylaluminum

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~%

Dichloroethylaluminum structure

Dichloroethylal...

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Chloro(diisobutyl)aluminum Structure

Chloro(diisobut...

CAS#:1779-25-5

Literature: Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 630, # 8-9 p. 1196 - 1204

 Customs

HS Code 2903199000
Summary 2903199000 other saturated chlorinated derivatives of acyclic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Synonyms

Aluminum, chlorobis(2-methylpropyl)-
iso-Bu2AlCl
MFCD00008927
Chlorodiisobutylaluminium
Dibac
EINECS 217-216-8
Chloro(diisobutyl)aluminium
chloro[bis(2-methylpropyl)]aluminum
diisobutylaluminium chloride
Chloro(diisobutyl)aluminum
Aluminum,chlorodiisobutyl
Diisobutylaluminum monochloride
Diisobutylaluminum chloride
chloro-diisobutylaluminum
Diisobutylchloroaluminum
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